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Methane conversion into aromatic hydrocarbons over Ag-Mo/ZSM-5 catalysts

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Abstract

Nonoxidative methane conversion into aromatic hydrocarbons over ZSM-5-type high-silica zeolites modified with nanosized powders of molybdenum (4.0 wt %) and silver (0.1–0.5 wt %) is reported. The acidic properties of the catalysts have been investigated by temperature-programmed ammonia desorption. The microstructure and composition of the Ag-Mo/ZSM-5 catalytic systems have been studied by high-resolution transmission electron microscopy and energy-dispersive X-ray spectroscopy. The doping of the Mocontaining zeolite with silver enhances its activity and stability in nonoxidative methane conversion into aromatic hydrocarbons.

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Authors and Affiliations

  1. Institute of Petroleum Chemistry, Siberian Branch, Russian Academy of Sciences, Tomsk, 634055, Russia

    A. V. Vosmerikov, L. L. Korobitsyna, V. V. Kozlov & N. V. Arbuzova

  2. Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090, Russia

    V. I. Zaikovskii

  3. Research Institute of High Voltages, Tomsk Polytechnic University, Tomsk, 634028, Russia

    S. P. Zhuravkov

Authors
  1. A. V. Vosmerikov
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  2. V. I. Zaikovskii
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  3. L. L. Korobitsyna
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  4. V. V. Kozlov
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  5. N. V. Arbuzova
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  6. S. P. Zhuravkov
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Corresponding author

Correspondence to A. V. Vosmerikov.

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Original Russian Text © A.V. Vosmerikov, V.I. Zaikovskii, L.L. Korobitsyna, V.V. Kozlov, N.V. Arbuzova, S.P. Zhuravkov, 2011, published in Kinetika i Kataliz, 2011, Vol. 52, No. 3, pp. 438–444.

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Vosmerikov, A.V., Zaikovskii, V.I., Korobitsyna, L.L. et al. Methane conversion into aromatic hydrocarbons over Ag-Mo/ZSM-5 catalysts. Kinet Catal 52, 427–433 (2011). https://doi.org/10.1134/S0023158411030190

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  • DOI: https://doi.org/10.1134/S0023158411030190

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