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Green chemistry in the bulk chemicals industry

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In memory of Mikhail Grigor’evich Kucherov, an outstanding organic chemist who discovered the first industrially important reaction catalyzed by metal complexes (to the 130th anniversary of the discovery in 1881 and to the 100th anniversary of the day he died in 1911).

Abstract

The bulk chemicals industry is a branch of the chemical industry whose assortment includes key organic synthesis products and intermediates. The world output of these products is as large as millions of tons. This scale requires the use of not only maximally inexpensive raw materials but also the most selective and energy-efficient processes for converting them into target products. This paper considers the examples of changing the sources of raw materials and developing catalysts and processes to minimize environmental disruption. The majority of these new processes have been introduced into industry well before the appearance of the term green chemistry; their development has been stimulated by not only environmental protection but also economic reasons.

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References

  1. Zinin, N.N., Bull. Sci. Acad. Sci. St. Petersbourg, 1842.

  2. Walden, P.I., Ocherk istorii khimii v Rossii (History of Chemistry in Russia), Odessa, 1917.

  3. Sheldon, R.A., in Catalytic Oxidation: Principles and Applications, Sheldon, R.A. and van Santen, R.A., Eds., London: World Scientific, 1995.

    Google Scholar 

  4. Gao, G., Tao, Y., and Jiang, J., Green Chem., 2008, vol. 10, p. 439.

    Article  CAS  Google Scholar 

  5. Smidt, J., Hafner, W., Jira, R., Sedlmeier, J., Sieber, R., Rütinger, R., and Kojer, H., Angew. Chem., 1959, vol. 71, p. 176.

    Article  CAS  Google Scholar 

  6. Moiseev, I.I., Vargaftik, M.N., and Syrkin, Ya.K., Dokl. Akad. Nauk SSSR, 1960, vol. 130, no. 4, p. 820.

    CAS  Google Scholar 

  7. Temkin, O.N., Gomogennyi metallokompleksnyi kataliz. Kineticheskie aspekty (Homogeneous Catalysis by Metal Complexes: Kinetic Aspects), Moscow: Akademkniga, 2008.

    Google Scholar 

  8. Halpern, J., in Advances in Catalysis and Related Subjects, Eley, D.D., Selwood, P.W., and Weisz, P.B., Eds, New York: Academic, 1959, vol. 11, p. 420.

    Google Scholar 

  9. Moiseev, I.I., π-Kompleksy v zhidkofaznom okislenii olefinov (π-Complexes in Liquid-Phase Alkene Oxidation), Moscow: Nauka, 1970.

    Google Scholar 

  10. Kovtun, G., Kameneva, T., Hladyi, S., Starchevsky, M., Pazdersky, Yu., Stolarov, I., Vargaftik, M., and Moiseev, I., Adv. Synth. Catal., 2002, vol. 344, no. 9, p. 957.

    Article  CAS  Google Scholar 

  11. Moiseev, I.I., Vargaftik, M.N., and Syrkin, Ya.K., Dokl. Akad. Nauk SSSR, 1960, vol. 133, no. 2, p. 377.

    CAS  Google Scholar 

  12. Weissermel, K. and Arpe, H.-J., Industrial Organic Chemistry, Weinheim: Wiley-VCH, 2003.

    Book  Google Scholar 

  13. Vargaftik, M.N., Zagorodnikov, V.P., Stolarov, I.P., Kochubey, D.I., Likholobov, V.A., Chuvilin, A.L., Moiseev, I.I., and Zamaraev, K.I., J. Mol. Catal., 1989, vol. 53, no. 3, p. 315.

    Article  CAS  Google Scholar 

  14. Vargaftik, M.N., Zagorodnikov, V.P., Stolyarov, I.P., Moiseev, I.I., Likholobov, V.A., Kochubey, D.I., Chuvilin, A.L., Zaikovsky V.I., Zamaraev, K.I., and Timofeeva, G.I., J. Chem. Soc., Chem. Commun., 1985, p. 937.

  15. Flid, M.R. and Treger, Yu.A., Vinilkhlorid: khimiya i tekhnologiya (Vinyl Chloride: Chemistry and Technology), Moscow: Kalvis, 2008.

    Google Scholar 

  16. Prilezhaeva, E.N., Reaktsiya Prilezhaeva: Elektrofil’noe okislenie (Prileschajew Reaction: Electrophilic Oxidation), Moscow: Nauka, 1974.

    Google Scholar 

  17. Fenton, H.I.H., J. Chem. Soc., 1894, vol. 65, p. 899.

    CAS  Google Scholar 

  18. Markov, A.A., Dolin, S.P., Moiseeva, N.I., Gekhman, A.E., and Moiseev, I.I., Mendeleev Commun., 2009, vol. 19, no. 4, p. 175.

    Article  CAS  Google Scholar 

  19. Brill, W.F., J. Am. Chem. Soc., 1963, vol. 85, p. 141.

    Article  CAS  Google Scholar 

  20. Gavrilenko, V.A., Evzerikhin, E.I., Kolosov, V.A., Larin, G.M., and Moiseev, I.I., Izv. Akad. Nauk SSSR, Ser. Khim., 1974, p. 1954.

  21. Gavrilenko, V.A., Evzerikhin, E.I., Kolosov, V.A., Larin, G.M., and Moiseev, I.I., Izv. Akad. Nauk SSSR, Ser. Khim., 1975, p. 2172.

  22. Gavrilenko, V.A., Evzerikhin, E.I., Kolosov, V.A., Larin, G.M., and Moiseev, I.I., Izv. Akad. Nauk SSSR, Ser. Khim., 1977, p. 29.

  23. Gavrilenko, V.A., Evzerikhin, E.I., Kolosov, V.A., Larin, G.M., and Moiseev, I.I., Izv. Akad. Nauk SSSR, Ser. Khim., 1977, p. 22.

  24. Gavrilenko, V.A., Evzerikhin, E.I., Kolosov, V.A., Larin, G.M., and Moiseev, I.I., Izv. Akad. Nauk SSSR, Ser. Khim., 1977, p. 1162.

  25. Gavrilenko, V.A., Evzerikhin, E.I., Kolosov, V.A., Larin, G.M., and Moiseev, I.I., Izv. Akad. Nauk SSSR, Ser. Khim., 1977, p. 1612.

  26. Sheldon, R.A., Recl. Trav. Chim. Pays-Bas, 1973, vol. 253, p. 367.

    Google Scholar 

  27. US Patent 4021454, 1977.

  28. Notari, B., Stud. Surf. Sci. Catal., 1991, vol. 67, p. 243.

    Article  CAS  Google Scholar 

  29. Catalysis from A to Z: A Concise Encyclopedia, Cornils, B., Herrmann, W.A., Schlögl, R., and Wong, C.-H., Eds. Weinheim: Wiley-VCH, 2000.

    Google Scholar 

  30. Eur. Patent 271.145 A2, 1988.

  31. Petrini, G., Leofanti, G., Mantegazza, M.A., and Pignataro, F., ACS Symp. Ser., 1996, vol. 626, p. 33.

    Article  CAS  Google Scholar 

  32. Isumi, Y., Ichihashi, H., Shimazu, Y., and Sato, H., Bull. Chem. Soc. Jpn., 2007, vol. 80, no. 7, p. 1280.

    Article  Google Scholar 

  33. Isumi, Y., Ichihashi, H., Shimazu, Y., and Kitamura, M., Chem. Eng. Jpn., 2004, vol. 68, p. 48.

    Google Scholar 

  34. Hock, H. and Lang, S., Ber. Chem. Ges., 1944, vol. 77B, p. 257.

    CAS  Google Scholar 

  35. Panov, G.I. and Kharitonov, A.S., Ross. Khim. Zh., 2000, vol. 44, no. 1, p. 7.

    CAS  Google Scholar 

  36. Pokhodenko, V.D. and Pavlishchuk, V.V., Teor. Eksp. Khim., 2002, vol. 38, no. 2, p. 67.

    Google Scholar 

  37. Sheldon, R.A., Arends, I., and Hanefeld, U., Green Chemistry and Catalysis, Weinheim: Wiley-VCH, 2007.

    Book  Google Scholar 

  38. http://bioethanol.ru/biodiesel/articles/algae-for-a-second-green-revolution/

  39. Graziani, M. and Fornasiero, P., Renewable Resources and Renewable Energy: A Global Challenge, London: CRC, 2007.

    Google Scholar 

  40. Edwards, M., Green Algae Strategy: End Oil Imports and Engineer Sustainable Food and Fuel, ISBN 1440421846, 2008.

  41. Moiseev, I.I., Tarasov, V.L., and Trusov, L.I., Chem. J., 2010, no. 7, p. 40.

  42. Bozell, J.J. and Petersen, G.R., Green Chem., 2010, vol. 12, p. 539.

    Article  CAS  Google Scholar 

  43. http://sustainabilityreport09.ganisco.com/index.dsp

  44. http://www.minprom.gov.ru/activity/chem./strateg/0

  45. Perspektivy energeticheskikh tekhnologii. V podderzhku plana deistvii “Gruppy vos’mi”. Stsenarii i strategii do 2050 g. OESR/MEA, WWF Rossii (Outlook for Energy Technologies: Supporting the Group of Eight’s Plan: OECD/IEA and WWF Russia’s Scenarios and Strategies up to the Year 2050), Kokorin, A.O. and Muratova, T.M., Eds., Moscow: OESR/MEA, 2007.

    Google Scholar 

  46. http://www.fastcompany.com/blog/ariel-schwartz/susta-nability/cereplast-turning-algae-green-plastic

  47. www1.eere.energy.gov/biomass/pdfs/algal-biofuels-road-map.pdf

  48. Newhouse, T., Baran, P.S., and Hoffmann, R.W., Chem. Soc. Rev., 2009, vol. 38, p. 3010.

    Article  CAS  Google Scholar 

  49. Beletskaya, I.P. and Kustov, L.M., Usp. Khim., 2010, vol. 79, no. 6, p. 493.

    Google Scholar 

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Correspondence to I. I. Moiseev.

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Original Russian Text © I.I. Moiseev, 2011, published in Kinetika i Kataliz, 2011, Vol. 52, No. 3, pp. 347–357.

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Moiseev, I.I. Green chemistry in the bulk chemicals industry. Kinet Catal 52, 337–347 (2011). https://doi.org/10.1134/S0023158411030141

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