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Photochromism of 6′-cyanosubstituted spirooxazines in frozen alcohol matrices

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Abstract

For three 6′-cyanosubstituted spironaphthooxazines, spectral characteristics of an open form and quantum yields of photoisomerization were determined both at room temperature and in frozen alcohol matrices. Spironaphthooxazines have demonstrated fairly high (0.01–0.02) quantum yields of open form appearance at 77 K. The observed peculiarities of the open form UV spectra were explained by the temperature dependence of the open form isomers distribution. Partial stabilization of the nonequilibrium isomers of an open form in the low-temperature matrices was revealed.

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Authors and Affiliations

  1. Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090, Russia

    M. I. Nikolaeva

  2. Institute of Chemical Kinetics and Combustion, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090, Russia

    V. V. Korolev, E. A. Pritchina, E. M. Glebov & V. F. Plyusnin

  3. Novosibirsk State University, Novosibirsk, 630090, Russia

    V. V. Korolev, E. A. Pritchina, E. M. Glebov & V. F. Plyusnin

  4. Institute of Physical and Organic Chemistry, Southern Federal University, Rostov-on-Don, 344090, Russia

    A. V. Metelitsa, N. A. Voloshin & V. I. Minkin

Authors
  1. M. I. Nikolaeva
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  2. V. V. Korolev
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  3. E. A. Pritchina
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  4. E. M. Glebov
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  5. V. F. Plyusnin
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  6. A. V. Metelitsa
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  7. N. A. Voloshin
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  8. V. I. Minkin
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Corresponding author

Correspondence to E. M. Glebov.

Additional information

Original Russian Text © M.I. Nikolaeva, V.V. Korolev, E.A. Pritchina, E.M. Glebov, V.F. Plyusnin, A.V. Metelitsa, N.A. Voloshin, V.I. Minkin, 2011, published in Kinetika i Kataliz, 2011, Vol. 52, No. 2, pp. 209–217.

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Nikolaeva, M.I., Korolev, V.V., Pritchina, E.A. et al. Photochromism of 6′-cyanosubstituted spirooxazines in frozen alcohol matrices. Kinet Catal 52, 202–209 (2011). https://doi.org/10.1134/S0023158411020145

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