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Hybrid polymer-immobilized palladium nanoparticles: Preparation and catalytic properties

Kinetics and Catalysis volume 52, pages 242–250 (2011)Cite this article

Abstract

A new approach to the synthesis of mixed-type immobilized catalysts was developed: the frontal polymerization of a metal-containing monomer in the presence of a highly dispersed mineral support. The synthesis of an acrylamide complex of Pd(II) nitrate on the surface of SiO2, Al2O3, or C and its subsequent polymerization and reduction resulted in the formation of an organic-inorganic composite that included nanosized Pd particles stabilized by a polymer matrix and an inorganic support. The resulting hybrid nanocomposites are efficient and selective catalysts for the hydrogenation reactions of cyclohexene and alkene and acetylene alcohols.

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Authors and Affiliations

  1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow oblast, 142432, Russia

    N. D. Golubeva, S. I. Pomogailo, G. I. Dzhardimalieva & A. D. Pomogailo

  2. Sokol’skii Institute of Organic Catalysis and Electrochemistry, Academy of Sciences of Kazakhstan, Almaty, Kazakhstan

    B. K. Dyusenalin, B. S. Selenova & A. K. Zharmagambetova

Authors
  1. N. D. Golubeva
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  2. B. K. Dyusenalin
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  3. B. S. Selenova
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  4. S. I. Pomogailo
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  5. A. K. Zharmagambetova
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  6. G. I. Dzhardimalieva
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  7. A. D. Pomogailo
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Corresponding author

Correspondence to G. I. Dzhardimalieva.

Additional information

Original Russian Text © N.D. Golubeva, B.K. Dyusenalin, B.S. Selenova, S.I. Pomogailo, A.K. Zharmagambetova, G.I. Dzhardimalieva, A.D. Pomogailo, 2011, published in Kinetika i Kataliz, 2011, Vol. 52, No. 2, pp. 250–258.

Communication no. 67 from the series Reactivity of Metal-Containing Monomers. For communication no. 66, see [1].

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Golubeva, N.D., Dyusenalin, B.K., Selenova, B.S. et al. Hybrid polymer-immobilized palladium nanoparticles: Preparation and catalytic properties. Kinet Catal 52, 242–250 (2011). https://doi.org/10.1134/S0023158411020078

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  • DOI: https://doi.org/10.1134/S0023158411020078

Keywords

  • Cyclohexene
  • Hydrogenation Reaction
  • Allyl Alcohol
  • Frontal Polymerization
  • Inorganic Support