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Hybrid polymer-immobilized palladium nanoparticles: Preparation and catalytic properties


A new approach to the synthesis of mixed-type immobilized catalysts was developed: the frontal polymerization of a metal-containing monomer in the presence of a highly dispersed mineral support. The synthesis of an acrylamide complex of Pd(II) nitrate on the surface of SiO2, Al2O3, or C and its subsequent polymerization and reduction resulted in the formation of an organic-inorganic composite that included nanosized Pd particles stabilized by a polymer matrix and an inorganic support. The resulting hybrid nanocomposites are efficient and selective catalysts for the hydrogenation reactions of cyclohexene and alkene and acetylene alcohols.

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Correspondence to G. I. Dzhardimalieva.

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Original Russian Text © N.D. Golubeva, B.K. Dyusenalin, B.S. Selenova, S.I. Pomogailo, A.K. Zharmagambetova, G.I. Dzhardimalieva, A.D. Pomogailo, 2011, published in Kinetika i Kataliz, 2011, Vol. 52, No. 2, pp. 250–258.

Communication no. 67 from the series Reactivity of Metal-Containing Monomers. For communication no. 66, see [1].

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Golubeva, N.D., Dyusenalin, B.K., Selenova, B.S. et al. Hybrid polymer-immobilized palladium nanoparticles: Preparation and catalytic properties. Kinet Catal 52, 242–250 (2011).

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  • Cyclohexene
  • Hydrogenation Reaction
  • Allyl Alcohol
  • Frontal Polymerization
  • Inorganic Support