Kinetics and Catalysis

, Volume 50, Issue 4, pp 577–582 | Cite as

Physicochemical study of catalysts for the oxidative dehydrogenation of isobutane: Cobalt, nickel, and manganese molybdates

  • Yu. A. Agafonov
  • N. V. Nekrasov
  • N. A. GaidaiEmail author
  • M. A. Botavina
  • P. E. Davydov
  • A. L. Lapidus


Temperature-programmed desorption and IR spectroscopic studies of the physicochemical properties of cobalt, nickel, and manganese molybdates are reported. These properties are correlated with the catalytic properties of the molybdates in the oxidative dehydrogenation of isobutane with atmospheric oxygen. It is demonstrated by an analysis of the IR spectra of the molybdates that the isobutene yield grows as the proportion of tetrahedrally coordinated molybdenum in the catalyst structure increases in isobutane dehydrogenation. NiMoO4 has the highest surface concentration of strong acid sites, and it binds adsorbed isobutene more strongly than the other catalysts


Molybdate Isobutane Temperature Programme Desorption Strong Acid Site Temperature Programme Desorption Spectrum 
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Copyright information

© Pleiades Publishing, Ltd. 2009

Authors and Affiliations

  • Yu. A. Agafonov
    • 1
  • N. V. Nekrasov
    • 1
  • N. A. Gaidai
    • 1
    Email author
  • M. A. Botavina
    • 1
  • P. E. Davydov
    • 1
  • A. L. Lapidus
    • 1
  1. 1.Zelinskii Institute of Organic ChemistryRussian Academy of SciencesMoscowRussia

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