Skip to main content
SpringerLink
Log in

Hydrocarbon oxidation with an oxygen-hydrogen mixture: Catalytic systems based on the interaction of platinum or palladium with a heteropoly compound

  • Fifty Years of the Boreskov Institute of Catalysis
  • Published:
Kinetics and Catalysis Aims and scope Submit manuscript

Abstract

A series of studies of hydrocarbon oxidation by the O2 + H2 mixture in the presence of catalytic systems based on Pt or Pd and a heteropoly compound (HPC) is reviewed. The catalytic systems were prepared from Pd(II) complexes with the heteropoly tungstate anions PW11O 7−29 and PW9O 9−34 , the complex salt [Pt(NH3)4][H2Mo12O40]2 · 7H2O, mixtures of H2PtCl4 or H2PtCl6 with H3 + n PMo12 − n V n O40 (n = 0–3) heteropoly acids, or supported platinum dispersed in HPC solutions. The interaction of metal ions and particles with HPCs in the initial state and after thermal and redox treatments was investigated by NMR, IR spectroscopy, XPS, EXAFS, HREM, and TPR. The catalytic systems were tested in the liquid-phase oxidation of alkanes, cyclohexane, cycloalkenes, benzene, toluene, and phenol with the O2 + H2 mixture at low temperatures. Effective supported catalysts based on platinum nanoparticles associated with the redox-active HPCs H3PMo12O40 and H4PMo11VO40 were prepared for gas-phase benzene oxidation into phenol. The oxidation mechanism includes the interaction between dioxygen and platinum (or palladium) and the participation of the HPC in the formation of active oxygen species of radical nature.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Han, Y.-F. and Lunsford, J.H., J. Catal., 2005, vol. 230, no. 2, p. 313.

    Article  CAS  Google Scholar 

  2. Chinta, S. and Lunsford, J.H., J. Catal., 2004, vol. 225, no. 1, p. 249.

    Article  CAS  Google Scholar 

  3. Lunsford, J.H., J. Catal., 2003, vol. 216, nos. 1–2, p. 455.

    Article  CAS  Google Scholar 

  4. Burch, R.P. and Ellis, R., Appl. Catal., B, 2003, vol. 42, no. 2, p. 203.

    Article  CAS  Google Scholar 

  5. Park, E.D., Hwang, Y.-S., and Lee, J.S., Catal. Commun., 2001, vol. 2, nos. 6–7, p. 187.

    Article  CAS  Google Scholar 

  6. Kuznetsova, N.I., Lisitsyn, A.S., Boronin, A.I., and Likholobov, V.A., Stud. Surf. Sci. Catal., 1990, vol. 55, p. 89.

    Article  Google Scholar 

  7. Otsuka, K. and Wang, Y., Appl. Catal., A, 2001, vol. 222, nos. 1–2, p. 145.

    CAS  Google Scholar 

  8. Min, J.-S., Ishige, H., Misono, M., and Mizuno, N., J. Catal., 2001, vol. 198, no. 1, p. 116.

    Article  CAS  Google Scholar 

  9. Park, E.D., Hwang, Y.-S., Lee, C.W., and Lee, J.S., Appl. Catal., A, 2003, vol. 247, no. 2, p. 269.

    Article  CAS  Google Scholar 

  10. Remias, J.E., Pavlosky, T.A., and Sen, A., J. Mol. Catal. A: Chem., 2003, vol. 203, nos. 1–2, p. 179.

    Article  CAS  Google Scholar 

  11. Misono, M., Chem. Commun., 2001, p. 1141.

  12. Kuznetsova, L.I., Maksimov, G.M., and Likholobov, V.A., Kinet. Katal., 1999, vol. 40, no. 5, p. 688 [Kinet. Catal. (Engl. Transl.), vol. 40, no. 5, p. 622].

    Google Scholar 

  13. Polyoxometalate Chemistry from Topology via Self-Assembly to Applications, Finke, R.G., Pope, M.T., and Müller, A., Eds., Dordrecht: Kluwer, 2001.

    Google Scholar 

  14. Hill, C.L. and Prosser-McCartha, C.M., Coord. Chem. Rev., 1995, vol. 143, p. 407.

    Article  CAS  Google Scholar 

  15. Kozhevnikov, I., Catalysis for Fine Chemical Synthesis, vol. 2: Catalysis by Polyoxometalates, Chichester: Wiley, 2002.

    Google Scholar 

  16. Kuznetsova, N.I., Kuznetsova, L.I., Likholobov, V.A., and Pez, G.P., Catal. Today, 2005, vol. 99, nos. 1–2, p. 193.

    Article  CAS  Google Scholar 

  17. Ehrich, H., Berndt, H., Pohl, M.-M., Jahnisch, K., and Baerns, M., Appl. Catal., A, 2002, vol. 230, nos. 1–2, p. 271.

    CAS  Google Scholar 

  18. Knoth, W.H., Domaille, P.J., and Harlow, R.L., Inorg. Chem., 1986, vol. 25, p. 1577.

    Article  CAS  Google Scholar 

  19. Maksimov, G.M., Maksimovskaya, R.I., and Matveev, K.I., Zh. Neorg. Khim., 1987, vol. 32, no. 4, p. 985.

    CAS  Google Scholar 

  20. Tourne, C.M., Tourne, G.F., and Zonnevijlle, F., J. Chem. Soc., Dalton Trans., 1991, p. 143.

  21. Neumann, R. and Khenkin, A.M., Inorg. Chem., 1995, vol. 34, no. 23, p. 5753.

    Article  CAS  Google Scholar 

  22. Kuznetsova, N.I., Detusheva, L.G., Kuznetsova, L.I., Fedotov, M.A., and Likholobov, V.A., J. Mol. Catal. A: Chem., 1996, vol. 114, nos. 1–3, p. 131.

    Article  CAS  Google Scholar 

  23. Kuznetsova, L.I., Kuznetsova, N.I., Detusheva, L.G., Fedotov, M.A., and Likholobov, V.A., J. Mol. Catal. A: Chem., 2000, vol. 158, no. 1, p. 429.

    Article  CAS  Google Scholar 

  24. Detusheva, L.G., Kuznetsova, L.I., Fedotov, M.A., Likholobov, V.A., Dovlitova, L.S., Vlasov, A.A., and Malakhov, V.V., Koord. Khim., 2001, vol. 27, no. 12, p. 890.

    Google Scholar 

  25. Pope, M.T., Heteropoly and Isopoly Oxometalates, Berlin: Springer, 1983.

    Google Scholar 

  26. Kuznetsova, N.I., Detusheva, L.G., Kuznetsova, L.I., Fedotov, M.A., and Likholobov, V.A., Kinet. Katal., 1992, vol. 33, no. 3, p. 516.

    CAS  Google Scholar 

  27. Kuznetsova, N.I., Kuznetsova, L.I., Detusheva, L.G., Likholobov, V.A., Fedotov, M.A., Koscheev, S.V., and Burgina, E.B., Stud. Surf. Sci. Catal., 1997, vol. 110, p. 1203.

    Article  CAS  Google Scholar 

  28. Pettersson, L., Andersson, I., and Öhman, L.-O., Inorg. Chem., 1986, vol. 25, p. 4726.

    Article  CAS  Google Scholar 

  29. Combs-Walker, L.A. and Hill, C.L., Inorg. Chem., 1991, vol. 30, p. 4016.

    Article  CAS  Google Scholar 

  30. Detusheva, L.G., Kuznetsova, L.I., Fedotov, M.A., Dovlitova, L.S., Vlasov, A.A., Likholobov, V.A., and Malakhov, V.V., Zh. Neorg. Khim., 2003, vol. 48, no. 11, p. 1835 [Russ. J. Inorg. Chem. (Engl. Transl.), vol. 48, no. 11, p. 1685].

    CAS  Google Scholar 

  31. Maksimov, G.M., Maksimovskaya, R.I., and Matveev, K.I., Zh. Neorg. Khim., 1997, vol. 42, no. 6, p. 990 [Russ. J. Inorg. Chem. (Engl. Transl.), vol. 42, no. 6, p. 892].

    CAS  Google Scholar 

  32. Maksimov, G.M., Zaikovskii, V.I., Matveev, K.I., and Likholobov, V.A., Kinet. Katal., 2000, vol. 41, no. 6, p. 925 [Kinet. Catal. (Engl. Transl.), vol. 41, no. 6, p. 844].

    Article  Google Scholar 

  33. Kirillova, N.V., Kuznetsova, N.I., Kuznetsova, L.I., Zaikovskii, V.I., Koscheev, S.V., and Likholobov, V.A., Catal. Lett., 2002, vol. 84, nos. 3–4, p. 163.

    Article  CAS  Google Scholar 

  34. Kirillova, N.V., Kuznetsova, N.I., Kuznetsova, L.I., and Likholobov, V.A., Izv. Akad. Nauk, Ser. Khim., 2002, no. 6, p. 894.

  35. Kunai, A., Kitano, T., Kuroda, Y., Li-Fen, J., and Sasaki, K., Catal. Lett., 1990, p. 139.

  36. Japanese Patent 6-256241, 1994.

  37. Japanese Patent 5-4935, 1993

  38. US Patent 5 426 245, 1993.

  39. Miyake, T., Hamada, M., Sasaki, Y., and Oguri, M., Appl. Catal., A, 1995, vol. 131, p. 33.

    Article  CAS  Google Scholar 

  40. Japanese Patent 5-320082, 1993.

  41. Kitano, T., Nakai, T., Nitta, M., Mori, M., Ito, S., and Sasaki, K., Bull. Chem. Soc. Jpn., 1994, vol. 67, no. 10, p. 2850.

    Article  CAS  Google Scholar 

  42. Niwa, S., Eswaramoorthy, M., Nair, J., Raj, A., Itoh, N., Shoji, H., Namba, T., and Mizukami, F., Science, 2002, vol. 295, p. 105.

    Article  CAS  Google Scholar 

  43. Kuznetsova, L.I., Kuznetsova, N.I., Koshcheev, S.V., Rogov, V.A., Zaikovskii, V.I., Novgorodov, B.N., Detusheva, L.G., Likholobov, V.A., and Kochubei, D.I., Kinet. Katal., 2006, vol. 47, no. 5, p. 728 [Kinet. Catal. (Engl. Transl.), vol. 47, no. 5, p. 704].

    Article  Google Scholar 

  44. Potapova, I.V., Kazanskii, L.P., and Spitsyn, V.I., in Issledovanie svoistv i primenenie geteropolikislot v katalize (Heteropoly Acids: Properties and Catalytic Applications), Yurchenko, E.N., Ed., Novosibirsk: Inst. Kataliza, 1978, p. 135.

    Google Scholar 

  45. Simonov, P.A., Troitskii, S.Yu., and Likholobov, V.A., Kinet. Katal., 2000, vol. 41, no. 2, p. 281 [Kinet. Catal. (Engl. Transl.), vol. 41, no. 2, p. 255].

    Google Scholar 

  46. Kuznetsova, N.I., Kuznetsova, L.I., Kirillova, N.V., Pokrovskii, L.M., Detusheva, L.G., Ansel, J.-E., and Likholobov, V.A., Izv. Akad. Nauk, Ser. Khim., 2003, no. 7, p. 1462.

  47. Kuznetsova, N.I., Kuznetsova, L.I., Kirillova, N.V., Detusheva, L.G., Likholobov, V.A., Khramov, M.I., and Ansel, J.-E., Kinet. Katal., 2005, vol. 46, no. 2, p. 219 [Kinet. Catal. (Engl. Transl.), vol. 46, no. 2, p. 204].

    Article  Google Scholar 

  48. Kuznetsova, N.I., Kirillova, N.V., Kuznetsova, L.I., and Likholobov, V.A., J. Mol. Catal. A: Chem., 2003, vols. 204–205, p. 591.

    Article  Google Scholar 

  49. Kuznetsova, N.I., Kirillova, N.V., Smirnova, M.J., Kuznetsova, L.I., and Likholobov, V.A., J. Hazard. Mater., 2007, vol. 146, p. 569.

    Article  CAS  Google Scholar 

  50. Odyakov, V.F., Kuznetsova, L.I., and Matveev, K.I., Zh. Neorg. Khim., 1978, vol. 23, no. 2, p. 457.

    CAS  Google Scholar 

  51. Fusi, A., Ugo, R., Fox, F., Pasini, A., and Senini, S., J. Organomet. Chem., 1971, vol. 26, p. 417.

    Article  CAS  Google Scholar 

  52. Yamase, T., Ishikawa, E., Asai, Y., and Konai, S., J. Mol. Catal. A: Chem., 1996, vol. 114, nos. 1–3, p. 237.

    Article  CAS  Google Scholar 

  53. Smith, J.R.L. and Norman, R.O.C., J. Chem. Soc., 1963, no. 5, p. 2897.

  54. Nomiya, K., Hashino, K., Nemoto, Y., and Watanabe, M., J. Mol. Catal. A: Chem., 2001, vol. 176, nos. 1–2, p. 79.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090, Russia

    N. I. Kuznetsova & L. I. Kuznetsova

Authors
  1. N. I. Kuznetsova
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. L. I. Kuznetsova
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to N. I. Kuznetsova.

Additional information

Original Russian Text © N.I. Kuznetsova, L.I. Kuznetsova, 2009, published in Kinetika i Kataliz, 2009, Vol. 50, No. 1, pp. 5–14.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kuznetsova, N.I., Kuznetsova, L.I. Hydrocarbon oxidation with an oxygen-hydrogen mixture: Catalytic systems based on the interaction of platinum or palladium with a heteropoly compound. Kinet Catal 50, 1–10 (2009). https://doi.org/10.1134/S0023158409010017

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0023158409010017

Keywords

Search

Navigation