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Stereoselective hydrogenation of acetylene on copper catalysts: A quantum-chemical study

  • III International Conference “Catalysis: Fundamentals and Applications”
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Abstract

The structure of the alkyne adsorption complex on the copper surface is favorable for the stereoselective formation of cis isomers in the hydrogenation reaction. The pathway of dissociative hydrogen adsorption on copper is reported. It is assumed that the electron-donating promoter acts to reduce the electron work function of the copper catalyst by partially covering or “decorating” the surface of the copper particles.

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Authors and Affiliations

  1. Institute of Organic Catalysis and Electrochemistry, Academy of Sciences of Kazakhstan, Almaty, Kazakhstan

    M. Zh. Zhaksibaev & A. M. Pak

  2. Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090, Russia

    S. E. Malykhin & Yu. V. Larichev

Authors
  1. M. Zh. Zhaksibaev
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  2. S. E. Malykhin
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  3. Yu. V. Larichev
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  4. A. M. Pak
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Corresponding author

Correspondence to S. E. Malykhin.

Additional information

Original Russian Text © M.Zh. Zhaksibaev, S.E. Malykhin, Yu.V. Larichev, A.M. Pak, 2008, published in Kinetika i Kataliz, 2008, Vol. 49, No. 4, pp. 552–555.

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Zhaksibaev, M.Z., Malykhin, S.E., Larichev, Y.V. et al. Stereoselective hydrogenation of acetylene on copper catalysts: A quantum-chemical study. Kinet Catal 49, 527–530 (2008). https://doi.org/10.1134/S0023158408040113

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  • DOI: https://doi.org/10.1134/S0023158408040113

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