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Kinetics and mechanism of the thermal decomposition of 1-bromo-4-nitroxymethylcubane

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Abstract

The thermal decomposition kinetics of 1-bromo-4-nitroxymethylcubane in the liquid phase is typical of C-ONO2 bond heterolysis, which occurs if the nitro ester has a strong donor substituent. A comparison between 1-bromo-4-nitroxymethylcubane and tert-butyl nitrate shows that bromocubyl is close to the tert-butyl group in induction properties and cubyl itself is a stronger donor than this group.

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Authors and Affiliations

  1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow oblast, 142432, Russia

    V. V. Dubikhin, V. G. Prokudin, L. D. Nazina, L. B. Romanova, L. T. Eremenko & G. M. Nazin

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  1. V. V. Dubikhin
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  2. V. G. Prokudin
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  3. L. D. Nazina
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  4. L. B. Romanova
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  5. L. T. Eremenko
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  6. G. M. Nazin
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Original Russian Text © V.V. Dubikhin, V.G. Prokudin, L.D. Nazina, L.B. Romanova, L.T. Eremenko, G.M. Nazin, 2007, published in Kinetika i Kataliz, 2007, Vol. 48, No. 3, pp. 365–367.

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Dubikhin, V.V., Prokudin, V.G., Nazina, L.D. et al. Kinetics and mechanism of the thermal decomposition of 1-bromo-4-nitroxymethylcubane. Kinet Catal 48, 345–347 (2007). https://doi.org/10.1134/S0023158407030020

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  • DOI: https://doi.org/10.1134/S0023158407030020

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