Abstract
We report a synthesis of a series of molecular compounds and coordination polymers of Zn2+, Mn2+ Cd2+, Eu3+, and Tb3+ with 4-allyl-2,3,5,6-tetrafluorobenzoic acid (4-Afb) anions and 1,10-phenanthroline with compositions [Zn(H2O)(phen)(4-Afb)2] (1), [Mn(H2O)(phen)(4-Afb)2]n·nH2O (2), [Cd(H2O)(phen)(4-Afb)2]n (3), [Cd(phen)(4-Afb)2]n (4), [Ln2(phen)2(4-Afb)6] (Ln = Eu 5Eu; Tb 5Tb). It is shown that the obtained cadmium coordination polymers have various compositions and structures, depending on crystallization conditions. The prepared compounds are characterized by single-crystal XRD, powder XRD, IR spectroscopy, and CHN analysis. Noncovalent interactions are analyzed using the Hirshfeld surface analysis. It is determined that the crystal packings is mainly stabilized by π⋯π, C–H⋯F, and C–F⋯π interactions. The photoluminescent properties of the 5Eu and 5Tb complexes are studied. It is shown that the structure-forming effects of non-covalent “arene–perfluoroarene” interactions can be possibly used for preorganizing reactive functional groups in the crystal.
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Russian Text © The Author(s), 2024, published in Zhurnal Strukturnoi Khimii, 2024, Vol. 65, No. 2, 122814.https://doi.org/10.26902/JSC_id122814
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Shmelev, M.A., Chistyakov, A.S., Razgonyaeva, G.A. et al. Synthesis, Structure, and Photoluminescent Properties of Zn2+, Mn2+, Cd2+, Eu3+, and Tb3+ Complexes with 4-Allyl-2,3,5,6-Tetrafluorobenzoic Acid Anions and 1,10-Phenanthroline. J Struct Chem 65, 362–380 (2024). https://doi.org/10.1134/S0022476624020148
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DOI: https://doi.org/10.1134/S0022476624020148