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SYNTHESIS, CRYSTAL STRUCTURE, SPECTROSCOPIC, LUMINESCENCE STUDIES AND HIRSHFELD SURFACE ANALYSIS OF BLUE LIGHT EMITTING HETEROMETALLIC MnIII–NiII COMPLEX

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Abstract

The synthesis, crystal structure, spectroscopic, luminescence properties and Hirshfeld surface analysis of a new heterometallic complex, [Mn(L)(H2O)(CH3CH2OH)]2[Ni(CN)4], (H2L = N,N′-bis(3,5-di-t-butylsalicylidene)-1,2-propanediamine) was reported. Single crystal diffraction measurements showed that the heterometallic MnIII–NiII complex consists of two [(Mn(L)(H2O)(CH3CH2OH)]+ cations and one [Ni(CN)4]2– anion. The Mn1 and Mn2 ions are hexacoordinate by N2O4 donor sets and have a distorted octahedral geometry. The 3D Hirshfeld surface and 2D fingerprint plots showed that the main interactions were the H⋯H intermolecular interactions with relative contributions of about 73.8%. According to solid-state luminescence measurements, the new heterometallic MnIII–NiII complex showed weak blue light emission.

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Text © The Author(s), 2023, published in Zhurnal Strukturnoi Khimii, 2023, Vol. 64, No. 9, 119200.https://doi.org/10.26902/JSC_id119200

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Gungor, E. SYNTHESIS, CRYSTAL STRUCTURE, SPECTROSCOPIC, LUMINESCENCE STUDIES AND HIRSHFELD SURFACE ANALYSIS OF BLUE LIGHT EMITTING HETEROMETALLIC MnIII–NiII COMPLEX. J Struct Chem 64, 1780–1794 (2023). https://doi.org/10.1134/S0022476623090214

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