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CRYSTAL STRUCTURE, SPECTRAL CHARACTERISATION AND THERMAL STUDY OF A NOVEL COMPOUND (Z)-3-((2-HYDROXYPROPYL) AMINO)-N,N-DIMETHYLBUT-2-ENAMIDE

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Abstract

A novel organic compound namely, (Z)-3-((2-hydroxypropyl)amino)-N,N-dimethylbut-2-enamide was synthesised by reacting N,N′-dimethylacetoacetamide (DMACAC) and 1-amino-2-propanol. The crystal structure of this compound was determined using single crystal X-ray diffraction method which revealed a planar geometry. Stabilisation of this compound by intramolecular hydrogen bonding is discussed. It was further characterised by TG-DTA, FTIR, NMR and Mass spectrometry. The compound was found to undergo a single step weight loss giving 1.7% residue at 320 °C in a high pure N2 atmosphere and melts in the temperature range of 119-122 °C.

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Authors and Affiliations

  1. Physics division, School of Advanced Sciences, Vellore Institute of Technology, Chennai, Republic of India

    S. Sindhu

  2. Chemistry Division, School of Advanced Sciences, Vellore Institute of Technology, Chennai, Republic of India

    S. Arockiasamy

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  1. S. Sindhu
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  2. S. Arockiasamy
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Correspondence to S. Arockiasamy.

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Text © The Author(s), 2023, published in Zhurnal Strukturnoi Khimii, 2023, Vol. 64, No. 9, 116731.https://doi.org/10.26902/JSC_id116731

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Sindhu, S., Arockiasamy, S. CRYSTAL STRUCTURE, SPECTRAL CHARACTERISATION AND THERMAL STUDY OF A NOVEL COMPOUND (Z)-3-((2-HYDROXYPROPYL) AMINO)-N,N-DIMETHYLBUT-2-ENAMIDE. J Struct Chem 64, 1677–1685 (2023). https://doi.org/10.1134/S0022476623090111

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