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AgNO3 COMPLEXES WITH DIPHENYL(2-PYRIMIDYL) PHOSPHINE: SYNTHESIS, STRUCTURE, LUMINESCENT PROPERTIES

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Abstract

The [Ag2L2(NO3)2]n·(CH3CN)n chained coordination polymer is prepared by the interaction of AgNO3 with diphenyl(2-pyrimidyl)phosphine (L) (1:1) due to the linking of [Ag2L2] fragments by bridging nitrate ions. At room temperature, this polymer exhibits weak blue-green photoluminescence with a quantum yield of 6% and a decay time of 19 µs. It is shown that the [Ag2L3(NO3)2] binuclear complex and the [Ag3L2(NO3)3]n·2(CH2Cl2)n layered coordination polymer are formed at the AgNO3/L molar ratio equal to 2:3 and 3:2, respectively. Based on the XRD data, molecular structures of all three obtained compounds are discussed.

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Funding

This work was funded by the Ministry of Science and Higher Education of the Russian Federation (projects No. 121031700321-3, 1021051503141-0-1.4.1).

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    M. I. Rogovoy & E. H. Sadykov

  2. Vorozhtsov Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    I. Y. Bagryanskaya

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Russian Text © The Author(s), 2023, published in Zhurnal Strukturnoi Khimii, 2023, Vol. 64, No. 9, 116486.https://doi.org/10.26902/JSC_id116486

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Rogovoy, M.I., Bagryanskaya, I.Y. & Sadykov, E.H. AgNO3 COMPLEXES WITH DIPHENYL(2-PYRIMIDYL) PHOSPHINE: SYNTHESIS, STRUCTURE, LUMINESCENT PROPERTIES. J Struct Chem 64, 1654–1663 (2023). https://doi.org/10.1134/S0022476623090093

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