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SYNTHESIS, CRYSTAL STRUCTURE, AND TOPOLOGY OF THE K4Sn2(Si6O18)·2H2O NEW MICROPOROUS STANOSILICATE WITH KOSTYLEVITE STRUCTURAL TYPE

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Abstract

Single crystals of a new synthetic K4Sn2(Si6O18)·2H2O stannosilicate are prepared by the intermediate-temperature hydrothermal synthesis in the K2CO3:SnO2:SiO2 system using the 2:1:2 weight ratio of components. The experiments are carried out for 14 days in standard steel autoclaves at T = 553 K and P = 7 MPa. The crystal structure is studied by the X-ray diffraction analysis. Monoclinic unit cell parameters: a = 6.4605(3) Å, b = 11.6357(5) Å, c = 12.9162(6) Å, β = 103.893(5)°; V = 942.54(8) Å3; space group P21/n. The new compound is isostructural to the K4Zr2(Si6O18)·2H2O kostylevite mineral and related synthetic compounds, in particular, the AV-7 material with the K3NaSn2(Si6O18)·2H2O composition. The crystal structure of the studied stannosilicate is formed by a heteropolyhedral framework characterized by the presence of a system of wide parallel channels arranged along the [100] direction. The new stannosilicate is the first representative of kostylevite-like compounds whose channels are filled only by potassium cations.

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Funding

This work was funded by the Russian Science Foundation (project No. 20-77-10065, topological analysis), and the State Assignment for FRC KSC RAS 122011300125-2 (X-ray diffraction analysis).

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Authors and Affiliations

  1. Faculty of Geology, Moscow State University, Moscow, Russia

    N. A. Yamnova, O. A. Gurbanova, A. S. Volkov, O. V. Dimitrova & D. V. Deyneko

  2. Laboratory of Arctic Mineralogy and Materials Science, FRC Kola Science Center, Russian Academy of Sciences, Apatity, Russia

    S. N. Volkov, D. V. Deyneko, Y. A. Vaitieva & S. M. Aksenov

  3. Institute of Experimental Mineralogy, Russian Academy of Sciences, Chernogolovka, Russia

    A. S. Volkov

  4. Geological Institute, FRC Kola Science Center, Russian Academy of Sciences, Apatity, Russia

    S. M. Aksenov

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Russian Text © The Author(s), 2023, published in Zhurnal Strukturnoi Khimii, 2023, Vol. 64, No. 9, 115285.https://doi.org/10.26902/JSC_id115285

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Yamnova, N.A., Volkov, S.N., Gurbanova, O.A. et al. SYNTHESIS, CRYSTAL STRUCTURE, AND TOPOLOGY OF THE K4Sn2(Si6O18)·2H2O NEW MICROPOROUS STANOSILICATE WITH KOSTYLEVITE STRUCTURAL TYPE. J Struct Chem 64, 1571–1581 (2023). https://doi.org/10.1134/S0022476623090019

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