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Tetrachlorosubstituted Lead Phthalocyanines: Effect of the Positions of Substituents on the Structure of Single Crystals and thin Films

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Abstract

The comparative study of the crystal structure and structural features of thermally sublimed films with lead phthalocyanines with chlorine substituents at peripheral (PbPcCl4-p) and non-peripheral positions of the phthalocyanine ring (PbPcCl4-np) is reported. It is shown that as for non-substituted phthalocyanine lead, in PbPcCl4-p and PbPcCl4-np molecules, the lead cation is out of the plane of the macrocycle. PbPcCl4-p crystallizes in the tetragonal crystal system (space group I4/m), and the PbPcCl4-p molecules are packed into vertical stacks along axis 4. The introduction of chlorine substituents into non-peripheral positions of the phthalocyanine ring causes a change in the crystal structure. PbPcCl4-np crystallizes in the space group P21/n, with PbPcCl4-np molecules being packed in layers along the b axis; inside one layer - in chains with alternating up and down orientations of lead atoms. The effect of the position of chlorine substituents on the microstructural features of PbPcСl4-p and PbPcCl4-np films is studied by powder X-ray diffraction and electronic absorption spectroscopy.

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The work was supported by the Russian Science Foundation (grant No. 22-73-00145).

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  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Science, Novosibirsk, Russia

    D. D. Klyamer, A. S. Sukhikh, D. V. Bonegardt & T. V. Basova

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Russian Text © The Author(s), 2023, published in Zhurnal Strukturnoi Khimii, 2023, Vol. 64, No. 4, 109409.https://doi.org/10.26902/JSC_id109409

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Klyamer, D.D., Sukhikh, A.S., Bonegardt, D.V. et al. Tetrachlorosubstituted Lead Phthalocyanines: Effect of the Positions of Substituents on the Structure of Single Crystals and thin Films. J Struct Chem 64, 650–661 (2023). https://doi.org/10.1134/S0022476623040121

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