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Synthesis, Crystal Structure, Hirshfeld Surface Analysis of bis(N,N-Diethylenediamine)Cadmium(II)] Dichloride

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Abstract

A new Cd(II) complex, bis[(N,N-diethylenediamine)cadmium(II)] dichloride, C12H32CdCl2N4, was synthesized by the reaction between cadmium(II) chloride hexahydrate, sodium hydroxide, and N,N-diethylenediamine in aqueous methanol. The crystal structure was characterized by single-crystal X-ray diffraction analysis technique. The crystal structure is monoclinic, space group P21/c with parameters a = 6.8959(3) Å, b = 16.0795(10) Å, c = 16.4406(8) Å, β = 100.23(4)°, V = 1794(16) Å3, Z = 4. The X-ray structure analysis reveals that the Cd(II) cation coordinated by four N atoms of the N,N-diethylenediamine units and two Cl atoms, giving it a octahedral geometry. In the crystal, the molecules are linked by N–H⋯Cl hydrogen bond, forming a three-dimensional supramolecular architecture. A Hirshfeld surface analysis was performed to record various intermolecular interactions, indicating the stabilization of the Cd(II) complex structure by the intermolecular weak N–H⋯Cl hydrogen bonds. The major interactions are H⋯H (80.2%) and Cl⋯H (19.8%) interactions for the title complex.

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  1. Department of Physics, Faculty of Arts and Sciences, Ondokuz Mayıs University, Samsun, Turkey

    N. Dege

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Text © The Author(s), 2023, published in Zhurnal Strukturnoi Khimii, 2023, Vol. 64, No. 4, 108562.https://doi.org/10.26902/JSC_id108562

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Dege, N. Synthesis, Crystal Structure, Hirshfeld Surface Analysis of bis(N,N-Diethylenediamine)Cadmium(II)] Dichloride. J Struct Chem 64, 563–570 (2023). https://doi.org/10.1134/S0022476623040042

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