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Crystallization Features of LiI-CrIII Coordination Compounds with Cyclobutane-1,1-Dicarboxylic Acid Anions

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Abstract

For the goal of preparing LiI–CrIII heterometallic coordination compounds, we studied the reaction of Cr(NO3)3·9H2O and Li2(cbdc) (obtained by the neutralization of LiOH·H2O and cyclobutane-1,1-dicarboxylic acid (H2cbdc)) interacting in the 1:3 ratio in aqueous and methanol solutions. It was found that synthesis in the aqueous medium and subsequent crystallization of the reaction solution results in a low yield (9%) of crystalline 2D polymeric compound {[CaLi6Cr4(OH)4(cbdc)8(H2O)16]·7H2O}n (1) formed due to the hydrolysis of a chromium(III) carboxylate complex and the introduction of Ca2+ ions penetrating into the structure as impurities in the initial LiOH·H2O compound. The use of methanol as a solvent in a similar reaction and subsequent long-term aging leads to the formation of crystals of [Li5Cr(cbdc)4(H2O)5]n (2, yield: 55%) whose 3D polymeric structure contains independent fragments with five Li+ ions and does not contain Ca2+ ions. The crystal structures of 1 and 2 are determined by single-crystal XRD (CCDC No. 2161744 (1), No. 2161745 (2)).

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Funding

This work was funded by the Russian Science Foundation (project No. 19-73-10181-P). The CHNS analysis, IR spectroscopy, and XRD analysis were performed using the equipment of the JRC PMR IGIC RAS.

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  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia

    E. S. Bazhina, M. A. Shmelev, M. A. Kiskin & I. L. Eremenko

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  1. E. S. Bazhina
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Russian Text © The Author(s), 2023, published in Zhurnal Strukturnoi Khimii, 2023, Vol. 64, No. 4, 108431.https://doi.org/10.26902/JSC_id108431

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Bazhina, E.S., Shmelev, M.A., Kiskin, M.A. et al. Crystallization Features of LiI-CrIII Coordination Compounds with Cyclobutane-1,1-Dicarboxylic Acid Anions. J Struct Chem 64, 550–562 (2023). https://doi.org/10.1134/S0022476623040030

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