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Synthesis and Structures of Mono- and Trinuclear Complexes of Palladium(II) with 2-Chloropyridine

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Abstract

New complex compounds[(2-clpy)2Pd(OOCMe)2] (I), [{(Ph)Pd(2-clpy)}2(OOCMe)4Pd]·3C6H6 (II), and [{(Ph)Pd(2-clpy)}2(OOCMe)4Pd] (III) are obtained in the interaction of palladium acetate [Pd3(OOCMe)6] with 2-chloropyridine (2-clpy) and structurally characterized by single crystal X-ray diffraction. It is found that in the inert medium, mononuclear compound I forms and it can be isolated in the crystalline state, while trinuclear complexes II and III are the products of benzene metalation with palladium under mild conditions.

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Scheme 1
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Funding

The work was supported by the Ministry of Science of the Russian Federation within the State Assignment for the Institute of General and Inorganic Chemistry, Russian Academy of Sciences.

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia

    I. A. Yakushev, N. K. Ogarkova, E. A. Sosunov, M. Yu. Nesterenko & A. S. Popova

  2. Peoples’ Friendship University of Russia (RUDN University), Moscow, Russia

    N. K. Ogarkova, E. K. Kultyshkina, T. A. Tereshina & A. S. Popova

  3. Higher Chemical College of the Russian Academy of Sciences, Mendeleev University of Chemical Technology, Moscow, Russia

    E. A. Sosunov & M. Yu. Nesterenko

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  1. I. A. Yakushev
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  2. N. K. Ogarkova
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Russian Text © The Author(s), 2023, published in Zhurnal Strukturnoi Khimii, 2023, Vol. 64, No. 3, 107273.https://doi.org/10.26902/JSC_id107273

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Yakushev, I.A., Ogarkova, N.K., Sosunov, E.A. et al. Synthesis and Structures of Mono- and Trinuclear Complexes of Palladium(II) with 2-Chloropyridine. J Struct Chem 64, 377–385 (2023). https://doi.org/10.1134/S0022476623030046

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