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COMPARATIVE XPS STUDY OF THE COMPOSITION AND ELECTRONIC STATE OF IRIDIUM IN BULK AND IMMOBILIZED BINUCLEAR [Ir(COD)Cl]2 COMPLEXES

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Abstract

Changes in the composition and electronic state of iridium in the [Ir(COD)Cl]2 complex, which are induced by X-ray radiation and oxidation by atmospheric oxygen, are studied by XPS.

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Funding

The authors are grateful to the Russian Science Foundation for the support of this study performed at the Institute of Catalysis, Siberian Branch, Russian Academy of Sciences (grant No. 19-13-00172-P).

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Authors and Affiliations

  1. Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    R. I. Kvon, A. V. Nartova, L. M. Kovtunova & V. I. Bukhtiyarov

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  1. R. I. Kvon
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  2. A. V. Nartova
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  3. L. M. Kovtunova
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  4. V. I. Bukhtiyarov
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Corresponding author

Correspondence to A. V. Nartova.

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The authors declare that they have no conflicts of interests.

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Russian Text © The Author(s), 2023, published in Zhurnal Strukturnoi Khimii, 2023, Vol. 64, No. 2, 106142.https://doi.org/10.26902/JSC_id106142

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Kvon, R.I., Nartova, A.V., Kovtunova, L.M. et al. COMPARATIVE XPS STUDY OF THE COMPOSITION AND ELECTRONIC STATE OF IRIDIUM IN BULK AND IMMOBILIZED BINUCLEAR [Ir(COD)Cl]2 COMPLEXES. J Struct Chem 64, 270–275 (2023). https://doi.org/10.1134/S0022476623020117

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