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COMPARATIVE CRYSTAL CHEMISTRY, SYMMETRY FEATURES, AND STRUCTURAL COMPLEXITY OF LiOH, NaOH, RbOH, CsOH, AND TlOH HYDROXIDES

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Abstract

We consider the structural features and symmetry of alkali metal (Li, Na, K, Rb, Cs) and thallium hydroxides crystallizing in LiOH, α-NaOH, β-NaOH, TlOH structure types. The complexities of crystal structures are calculated. The structure of these compounds is based on the alternation of dense layers with strong metal–oxygen bonds and the interlayer space. The common features of hydroxide structures is the location of atoms at square network nodes. Atoms are bound the networks by both true symmetry elements of space groups and additional pseudo-symmetry elements, which indicates the order-disorder (OD) character of hydroxide structures. The arrangement of atoms by the square network pattern allows the consideration of these compounds as a uniform group whose structures retain the tetragonal character of the initial LiOH structure, which is expressed in the similarity of horizontal parameters of their unit cells.

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Funding

The work was supported by Russian Science Foundation grant No. 20-77-10065 (symmetry features and polytypism - A. M. Banaru and S. M. Aksenov) and the State Assignment for the Vernadsky Institute of Ceochemistry and Analytical Chemistry, Russian Academy of Sciences (calculation of information indices - D.A. Banaru) and the Kola Science Center, Russian Academy of Sciences, No. 122011300125-2 (A. M. Banaru and S. M. Aksenov).

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Authors and Affiliations

  1. Moscow State University, Moscow, Russia

    N. A. Yamnova & A. M. Banaru

  2. Vernadsky Institute of Geochemistry and Analytical Chemistry, Russian Academy of Sciences, Moscow, Russia

    D. A. Banaru

  3. Laboratory of Arctic Mineralogy and Materials Science, Federal Research Center, Kola Science Center, Russian Academy of Sciences, Apatity, Russia

    A. M. Banaru & S. M. Aksenov

  4. Geological Institute, Federal Research Center, Kola Science Center, Russian Academy of Sciences, Apatity, Russia

    S. M. Aksenov

Authors
  1. N. A. Yamnova
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  2. D. A. Banaru
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  4. S. M. Aksenov
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Corresponding author

Correspondence to S. M. Aksenov.

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Russian Text © The Author(s), 2022, published in Zhurnal Strukturnoi Khimii, 2022, Vol. 63, No. 12, 103704.https://doi.org/10.26902/JSC_id103704

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Yamnova, N.A., Banaru, D.A., Banaru, A.M. et al. COMPARATIVE CRYSTAL CHEMISTRY, SYMMETRY FEATURES, AND STRUCTURAL COMPLEXITY OF LiOH, NaOH, RbOH, CsOH, AND TlOH HYDROXIDES. J Struct Chem 63, 2054–2067 (2022). https://doi.org/10.1134/S0022476622120174

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