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VARIETY OF METAL-ORGANIC FRAMEWORKS BASED ON CADMIUM(II) AND BITHIOPHENEDICARBOXYLIC ACID

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Abstract

Five novel metal-organic frameworks [Cd3(btdc)3(bpa)(dmf)2] (1), [Cd3(btdc)3(dabco)(dmf)2]·3DMF·H2O (2), [Cd2(btdc)2] (3), [Cd3(btdc)3(dmf)4]·5DMF (4), and [Cd(btdc)(dmf)2]·DMF (5) (H2btdc = 2,2′-bithiophene-5,5′-dicarboxylic acid; bpa = 1,2- bis(4-pyridyl)ethane; dabco = 1,4-diazabicyclo[2.2.2]octane; DMF = N,N-dimethylformamide) are prepared in solvothermal conditions. The structures are determined by single-crystal XRD. Compound 1 is characterized by powder XRD, elemental analysis, thermogravimetric analysis, and IR spectroscopy.

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Funding

This work was funded by the Russian Science Foundation (project No. 18-13-00203, https://rscf.ru/project/18-13-00203/).

The analysis of the studied compound was funded by the Ministry of Science and Higher Education of the Russian Federation (project No. 121031700321-3).

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    V. A. Dubskikh, A. A. Lysova, D. G. Samsonenko, D. N. Dybtsev & V. P. Fedin

  2. National Research Center “Kurchatov Institute”, Moscow, Russia

    P. V. Dorovatovskii & V. A. Lazarenko

Authors
  1. V. A. Dubskikh
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  2. A. A. Lysova
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  3. D. G. Samsonenko
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  4. P. V. Dorovatovskii
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  5. V. A. Lazarenko
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  6. D. N. Dybtsev
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  7. V. P. Fedin
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Corresponding author

Correspondence to D. N. Dybtsev.

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Additional information

Russian Text © The Author(s), 2022, published in Zhurnal Strukturnoi Khimii, 2022, Vol. 63, No. 11, 101883.https://doi.org/10.26902/JSC_id101883

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Dubskikh, V.A., Lysova, A.A., Samsonenko, D.G. et al. VARIETY OF METAL-ORGANIC FRAMEWORKS BASED ON CADMIUM(II) AND BITHIOPHENEDICARBOXYLIC ACID. J Struct Chem 63, 1831–1839 (2022). https://doi.org/10.1134/S0022476622110130

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