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SYNTHESIS, SPECTRAL CHARACTERIZATION, CRYSTAL STRUCTURE AND ANTIBACTERIAL ACTIVITY OF DICHLORO-{2-[(4-FLUOROPHENYL) IMINOMETHYL]PYRIDINE-κ2N,N′}MERCURY(II)

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Abstract

The title complex has been prepared using (4-fluoro-phenyl)-pyridin-2-ylmethylene-amine bidentate Schiff base ligand (L) and HgCl2. The Hg(II) center in the title compound, [HgCl2(C12H9FN2)], is covalently bonded to three Cl atoms and two N atoms of the diimine ligand. Mercury ion mononuclear fragment that forms a polymeric structure due to bridging chloride ligands is in a distorted trigonal-bipyramidal coordination environment formed by the bis-chelating N-heterocyclic ligand, two bridging Cl ligands and one terminal Cl ligand. One of the bridging Hg–Cl bonds is significantly longer than the other. In the crystal, weak C–H⋯Cl hydrogen bonds are observed in addition to π–π stacking interactions. It crystallizes in the orthorhombic space group P212121 with a = 7.2248(3) Å, b = 8.7713(3) Å, c = 20.0217(7) Å, α = 90.00°, β = 90.00°, γ = 90.00°, V = 1268.79(8) Å3, R1 = 0.023 and wR2 = 0.062 (I > 2σ(I)]. The antibacterial activities of the complex, ligand and metal salt were tested against Gram-positive bacteria Staphylococcus aureus and Gram-negative bacteria Escherichia coli studied by disk diffusion method.

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Authors and Affiliations

  1. Applied Science and Technology High Education Center; Academic Center for Education, Culture and Research (ACECR), Ahvaz, Iran

    M. Aminian

  2. Department of Chemistry, Buinzahra Branch, Islamic Azad University, Buinzahra, Iran

    M. Khalaj

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  1. M. Aminian
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  2. M. Khalaj
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Text © The Author(s), 2022, published in Zhurnal Strukturnoi Khimii, 2022, Vol. 63, No. 11, 101498.https://doi.org/10.26902/JSC_id101498

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Aminian, M., Khalaj, M. SYNTHESIS, SPECTRAL CHARACTERIZATION, CRYSTAL STRUCTURE AND ANTIBACTERIAL ACTIVITY OF DICHLORO-{2-[(4-FLUOROPHENYL) IMINOMETHYL]PYRIDINE-κ2N,N′}MERCURY(II). J Struct Chem 63, 1797–1801 (2022). https://doi.org/10.1134/S0022476622110099

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