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ACTIVE DIELECTRICS BASED ON COMPLEX ZIRCONIUM MOLYBDATES

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Abstract

This work summarizes results of a study of the structure and properties of double and triple molybdates in M2MoO4–R2(MoO4)3–Zr(MoO4)2 systems (M = K, Rb, Cs, R is a triply charged cation). Features of the formation of new double and triple molybdates LnxZry(MoO4)z (Ln = La–Lu, Y) and MaRbZrc(MoO4)d (M = K, Rb, Cs; R = Ln, R3+) are revealed, the corresponding single crystals are prepared, their structures are determined. Crystallographic, thermal, and electrophysical characteristics of individual phases are determined. The “composition–structure–properties” relation in the systems is established.

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REFERENCES

  1. M. V. Mokhosoev, F. P. Alekseev, and V. I. Lutsyk. Diagrammy sostoyaniya molibdatnykh i volframatnykh sistem (State Diagrams of Molybdate and Tungstate Systems). Novosibirsk, Russia: Nauka, 1978. [In Russian]

  2. M. V. Mokhosoev, F. P. Alekseev, and V. L. Butukhanov. Dvoinye molibdaty i volframaty (Double molybdates and tungstates). Novosibirsk, Russia: Nauka, 1981. [In Russian]

  3. V. K. Trunov, V. A. Efremov, and Yu. A. Velikodny. Kristallokhimiya i svoistva dvoinykh molibdatov i volframatov (Crystal Chemistry and Properties of Double Molybdates and Tungstates). Leningrad, Russia: Nauka, 1986. [In Russian]

  4. M. V. Mokhosoev and J. G. Bazarova. Slozhnye oksidy molibdena i volframa s elementami I-IV grupp (Complex Oxides of Molybdenum and Tungsten with I-IV Groups Elements). Moscow: Nauka, 1990. (In Russ.)

  5. K. I. Petrov, M. E. Poloznikova, Kh. T. Sharipov, and V. V. Fomichev. Kolebatelnye spektry molibdatov i volframatov (Vibrational Spectra of Molybdates and Tungstates). Tashkent: FAN, 1990. [In Russian]

  6. A. A. Evdokimov, V. A. Efremov, V. K. Trunov, I. A. Kleinman, and B. F. Dzhurinskii. Soedineniya redkozemelnykh elementov. Molibdaty, volframaty (Compounds of Rare Earth Elements. Molybdates, Tungstates). Moscow: Nauka, 1991. [In Russian]

  7. M. V. Provotorov, T. P. Balakireva, A. N. Egorova, A. I. Zagumenny, and A. A. Mayer. Trudy MHTI im. D. I. Mendeleeva (Proceedings of the D. I. Mendeleev Moscow Chemical Technology Institute). Moscow: Mendeleev Moscow Chemical Technology Institute, 1981. [In Russian]

  8. N. M. Kozhevnikova. Troinye molibdaty (Triple molybdates). Ulan-Ude, Russia: Buryat State University, 2000. [In Russian]

  9. A. P. Perepelitsa and S. G. Nedelko. Zh. Prikl. Khim.., 1996, 69, 684. [In Russian]

  10. V. V. Sokolov and E. M. Uskov. Khim. Interesakh Ustoich. Razvit., 2000, 1/2, 281. [In Russian]

  11. S. Dorzhieva, I. Chumak, A. Sarapulova, D. Mikhailova, J. Bazarova, and H. Erenberg. Acta Crystallogr., Sect. C, 2011, 67, I50. https://doi.org/10.1107/S0108270111033713

    Article  CAS  PubMed  Google Scholar 

  12. B. Glorier, V. Jubera, A. Afeseiksborde, and A. Garcia. Solid State Sci., 2011, 2, 460. https://doi.org/10.1016/j.solidstatesciences.2010.12.013

    Article  CAS  Google Scholar 

  13. V. V. Atuchin, V. G. Grossman, S. V. Adychev, N. V. Surovtsev, T. A. Gavrilova, and B. G. Bazarov. Opt. Mater., 2012, 5, 812. https://doi.org/10.1016/j.optmat.2011.11.016

    Article  CAS  Google Scholar 

  14. Z. Wang, H. Liang, M. Gong, and Q. Su. J. Alloys Compd., 2007, 1/2, 308. https://doi.org/10.1016/S0925-8388(07)00485-9

    Article  Google Scholar 

  15. J. Cortese, D. Abeysinghe, M. D. Smith, and H.-C. zur Loye. J. Solid State Chem., 2016, 240, 76. https://doi.org/10.1016/j.jssc.2016.05.007

    Article  CAS  Google Scholar 

  16. V. Mahalingam, J. Tirumalai, R. Krishnan, and S. Manta. Spectrochim. Acta, Part A, 2016, 152, 172. https://doi.org/10.1016/j.saa.2015.06.129

    Article  CAS  Google Scholar 

  17. Yu. L. Suponitskii, O. P. Proshina, A. G. Dyunin, and S. E. Lyashenko. Russ. J. Phys. Chem., 2016, 90, 267. https://doi.org/10.1134/S003602441602031X

    Article  CAS  Google Scholar 

  18. X. Deng, J. Tao, X. Yang, H. Ma, J. W. Richardson, and X. Zhao. Chem. Mater., 2008, 20(5), 1733. https://doi.org/10.1021/cm071605y

    Article  CAS  Google Scholar 

  19. R. Mittal, S. L. Chaplot, N. P. Lallab, and R. K. Mishrak. J. Appl. Crystallogr., 1999, 100, 1010. https://doi.org/10.1107/S0021889899008109

    Article  CAS  Google Scholar 

  20. R. F. Klevtsova, S. F. Solodovnikov, Yu. L. Tushinova, B. G. Bazarov, L. A. Glinskaya, and J. G. Bazarova. J. Struct. Chem., 2000, 41(2), 280. https://doi.org/10.1007/BF02741593

    Article  CAS  Google Scholar 

  21. J. G. Bazarova, Yu. L. Tushinova, B. G. Bazarov, K. N. Fedorov, R. F. Klevtsova, S. F. Solodovnikov, N. A. Pylneva, and N. A. Yurkin. Zh. Neorg. Khim., 2001, 46, 135. [In Russian]

  22. B. G. Bazarov, Yu. L. Tushinova, K. N. Fedorov, and J. G. Bazarova. Zh. Neorg. Khim., 2003, 48, 1414. [In Russian]

  23. V. G. Grossman, B. G. Bazarov, R. F. Klevtsova, J. G. Bazarova, and L. A. Glinskaya. Vestn. Buryat. Gos. Univ.: Khim., Fiz., 2012, 23. [In Russian]

  24. S. G. Dorzhieva, Yu. L. Tushinova, B. G. Bazarov, A. I. Nepomnyashchikh, R. Yu. Shendrik, and J. G. Bazarova. Bull. Russ. Acad. Sci. Phys., 2015, 79, 276. https://doi.org/10.3103/S1062873815020070

    Article  CAS  Google Scholar 

  25. B. G. Bazarov, J. G. Bazarova, Yu. L. Tushinova, L. A. Solovyov, S. G. Dorzhieva, E. Surenyav, and J. Temujin. J. Alloys Compd., 2017, 701, 750. https://doi.org/10.1016/j.jallcom.2017.01.173

    Article  CAS  Google Scholar 

  26. J. G. Bazarova, E. Yu. Badmaeva, S. F. Solodovnikov, and E. S. Zolotova. Russ. J. Inorg. Chem., 2004, 49, 284.

  27. Yu. L. Tushinova. Fazoobrazovanie v sistemakh Ln2O3–ZrO2–MoO3 (Ln = La–Lu, Y, Sc) (Phase Formation in Systems Ln2O3–ZrO2–MoO3 (Ln = La–Lu, Y, Sc)): Cand. (Chem.) Dissertation. Irkutsk, Russia: Irkutsk State University, 2005. [In Russian]

  28. G. A. Bandurkin, B. F. Dzhurinsky, I. V. Tananaev, and V. I. Pakhomov. Osobennosti kristallokhimii soedinenii redkozemelnykh elementov (Crystal Chemistry Features of Rare-Earth ElementsCompounds). Moscow: Nauka, 1984. [In Russian]

  29. J. G. Bazarova, Yu. L. Tushinova, B. G. Bazarov, and S. G. Dorzhieva. Russ. Chem. Bull., 2017, 4, 587. https://doi.org/10.1007/s11172-017-1777-9

    Article  CAS  Google Scholar 

  30. R. F. Klevtsova, J. G. Bazarova, L. A. Glinskaya, B. G. Bazarov, K. N. Fedorov, and P. V. Klevtsov. J. Struct. Chem., 1995, 36(5), 809. https://doi.org/10.1007/BF02579673

    Article  Google Scholar 

  31. S. F. Solodovnikov, E. S. Zolotova, B. G. Bazarov, Yu. L. Tushinova, J. G. Bazarova, and E. Yu. Badmaeva. J. Struct. Chem., 2004, 45(4), 657. https://doi.org/10.1007/s10947-005-0041-6

    Article  CAS  Google Scholar 

  32. F. Baur and T. Justel. Aust. J. Chem., 2015, 68, 1727. https://doi.org/10.1071/CH15268

    Article  CAS  Google Scholar 

  33. Q. Shuyun, H. Yanlin, C. Han, and J. S. Hyo. Electron. Mater. Lett., 2016, 12, 171. https://doi.org/10.1007/s13391-015-5244-1

    Article  CAS  Google Scholar 

  34. H. Y.-P. Hong. Mater. Res. Bull., 1976, 11, 173. https://doi.org/10.1016/0025-5408(76)90073-8

    Article  CAS  Google Scholar 

  35. S. G. Dorzhieva, B. G. Bazarov, A. A. Bush, K. E. Kamentsev, and J. G. Bazarova. J. Solid State Commun., 2015, 217, 25. https://doi.org/10.1016/j.ssc.2015.05.015

    Article  CAS  Google Scholar 

  36. S. G. Dorzhieva, B. G. Bazarov, A. K. Subanakov, and J. G. Bazarova. J. Solid State Chem., 2013, 199, 21. https://doi.org/10.1016/j.jssc.2012.11.023

    Article  CAS  Google Scholar 

  37. A. V. Logvinova, B. G. Bazarov, Yu. L. Tushinova, and J. G. Bazarova. Usp. Sovrem. Estestvozn., 2016, 10, 14. [In Russian]

  38. A. V. Logvinova, B. G. Bazarov, Yu. L. Tushinova, and J. G. Bazarova. Inorg. Mater., 2017. 53, 1286. https://doi.org/10.1134/S0020168517120081

    Article  CAS  Google Scholar 

  39. J. G. Bazarova, A. V. Logvinova, B. G. Bazarov, Yu. L. Tushinova, S. G. Dorzhieva, and J. Temuujin. J. Alloys Compd., 2018, 741, 834. https://doi.org/10.1016/j.jallcom.2018.01.208

    Article  CAS  Google Scholar 

  40. B. G. Bazarov, R. F. Klevtsova, Ts. T. Bazarova, L. A. Glinskaya, K. N. Fedorov, and J. G. Bazarova. Zh. Neorg. Khim., 2005, 50, 1240. [In Russian]

  41. B. G. Bazarov, A. D. Tsyrendorzhieva, Zh. G. Bazarova, R. F. Klevtsova, and L. A. Glinskaya. J. Struct. Chem, 2004, 45, 993. https://doi.org/10.1007/s10947-005-0091-9

    Article  CAS  Google Scholar 

  42. L. I. Gongorova. Fazovye ravnovesiya, stroyenie i svoystva novykh molibdatov v sistemakh Rb2MoO4–Ln2(MoO4)3–Zr(MoO4)2 (Ln = La–Lu) (Phase Equilibria, Structure and Properties of New Molybdates in Rb2MoO4–Ln2(MoO4)3–Zr(MoO4)2 (Ln = La–Lu) Systems): Cand. (Chem.) Dissertation. Irkutsk, Russia: Irkutsk State University, 2012. [In Russian]

  43. J. G. Bazarova, A. V. Logvinova, and B. G. Bazarov. Inorg. Mater., 2020, 56, 1350. https://doi.org/10.31857/S0002337X20120040

    Article  Google Scholar 

  44. J. G. Bazarova, A. V. Logvinova, and B. G. Bazarov. Izv. Vuzov, Prikl. Khim. Biotekhnol., 2021, 11, 508. [In Russian] https://doi.org/10.21285/2227-2925-2021-11-4-508-516

    Article  CAS  Google Scholar 

  45. T. V. Namsaraeva. Fazovye ravnovesiya, kristallicheskie struktury i svoistva novykh dvoinykh i troinykh molibdatov v sistemakh Cs2MoO4–R2(MoO4)3–Zr(MoO4)2 (R = Al, Cr, Fe, In, Sc, Bi) (Phase Equilibria, Crystal Structures and Properties of New Double and Triple Molybdates in Cs2MoO4–R2(MoO4)3–Zr(MoO4)2 (R = Al, Cr, Fe, In, Sc, Bi) Systems): Cand. (Chem.) Dissertation. Irkutsk, Russia: Irkutsk State University, 2010. [In Russian]

  46. J. G. Bazarova, Yu. L. Tushinova, B. G. Bazarov, B. E. Oyun, and J. D. Angarkhaev. Izv. Vuzov, Prikl. Khim. Biotekhnol., 2018, 8, 19. [In Russian] https://doi.org/10.21285/2227-2925-2018-8-2-19-28

    Article  CAS  Google Scholar 

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Funding

The study was carried out within the State Assignment for BINM SB RAS No. 0273-2021-0008.

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Authors and Affiliations

  1. Baikal Institute of Nature Management, Siberian Branch, Russian Academy of Scienses, Ulan-Ude, Russia

    Zh. G. Bazarova, A. K. Subanakov & B. G. Bazarov

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  1. Zh. G. Bazarova
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Correspondence to Zh. G. Bazarova.

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Russian Text © The Author(s), 2022, published in Zhurnal Strukturnoi Khimii, 2022, Vol. 63, No. 10, 100164.https://doi.org/10.26902/JSC_id100164

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Bazarova, Z.G., Subanakov, A.K. & Bazarov, B.G. ACTIVE DIELECTRICS BASED ON COMPLEX ZIRCONIUM MOLYBDATES. J Struct Chem 63, 1678–1696 (2022). https://doi.org/10.1134/S0022476622100146

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