Skip to main content
SpringerLink
Log in

STRUCTURE OF XPS SPECTRA OF K2FeO4

  • Published:
Journal of Structural Chemistry Aims and scope Submit manuscript

Abstract

An intricate structure of the X-ray photoelectron spectra of valence and core electrons of potassium ferrate (VI) (K2FeO4) containing Fe6+ ions (3d2) is studied for the first time. Binding energies of core electrons Eb(Fe 3p3/2) = 57.8 eV and Eb(Fe 2p3/2) = 712.1 eV are determined. The mechanism of the appearance of the structure in the Fe 3s spectrum is investigated. The experimental Fe 3s spectrum of Fe6+(3d2) cations in K2FeO4 consists mainly of two lines with a splitting of 2.1 eV. This value is consistent with the results of the theoretical calculation (2.6 eV) for 3d2 (Fe6+) performed by the configuration interaction method.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11
Fig. 12

Similar content being viewed by others

REFERENCES

  1. J. Q. Jiang. J. Hazard. Mater., 2007, 146, 617. https://doi.org/10.1016/j.jhazmat.2007.04.075

    Article  CAS  PubMed  Google Scholar 

  2. S. Wang, Z. Yang, D. Liu, S. Yi, and W. Chi. Electrochem. Commun., 2010, 12, 367. https://doi.org/10.1016/j.elecom.2009.12.036

    Article  CAS  Google Scholar 

  3. S. K. Y. D. M. A. and A. M. Russ. J. Inorg. Chem., 2010, 54(6), 942. https://doi.org/10.1134/S0036023610060185

    Article  CAS  Google Scholar 

  4. V. V. Nemoshkalenko and V. G. Aleshin. Elektronnaya spektroskopiya kristallov (Electron Spectroscopy of Crystals). Kiev: Naukova Dumka, 1976. [In Russian]

  5. P. S. Bagus, H. J. Freund, T. Minerva, G. Pacchioni, and F. Parmigiani. Chem. Phys. Lett., 1996, 25(1), 90. https://doi.org/10.1016/0009-2614(96)00070-X

    Article  CAS  Google Scholar 

  6. A. Yu. Teterin, K. I. Maslakov, Yu. A. Teterin, S. N. Kalmykov, K. E. Ivanov, L. Vukcevic, A. B. Khasanova, and N. S. Shcherbina. Russ. J. Inorg. Chem., 2006, 51(12), 1937. https://doi.org/10.1134/S0036023606120151

    Article  Google Scholar 

  7. Y. A. Teterin, A. V. Sobolev, A. A Belik, Y. S. Glazkova, K. I. , V. G. , . Teterin, K. E. , and I. A. . JETP, 2019, 128, 6. https://doi.org/10.1134/S1063776119050066

    Article  CAS  Google Scholar 

  8. V. G. Yarzhemsky, Yu. A. Teterin, I. A. Presnyakov, K. I. Maslakov, A. Yu. Teterin, and K. E. Ivanov. JETP Lett., 2020, 111(8), 422. 10.1134/S0021364020080135

    Article  CAS  Google Scholar 

  9. Yu. A. Teterin, A. V. Sobolev, I. A. Presnyakov, K. I. Maslakov, A. Yu. Teterin, I. V. Morozov, I. O. Chernyavskii, K. E. Ivanov, and A. V. Shevelkov. JETP, 2017, 124(2), 251. 10.1134/S1063776117010174

    Article  CAS  Google Scholar 

  10. V. G. Yarzhemsky, Yu. A. Teterin, K. I. Maslakov, A. Yu. Teterin, and K. E. Ivanov. JETP Lett., 2021, 114(10), 609. 10.1134/S0021364021220136

    Article  CAS  Google Scholar 

  11. L. N. Kramer and M. P. Klein. J. Chem. Phys., 1969, 51, 3618. https://doi.org/10.1063/1.1672562

    Article  CAS  Google Scholar 

  12. H. Konno and M. Nagayama. J. Electron. Spectrosc. Relat. Phenom., 1980, 18, 341. 10.1016/0368-2048(80)80021-1

    Article  CAS  Google Scholar 

  13. B. Lei, G. Zhou, T. Cheng, and J. Du. Asian J. Chem., 2013, 25(1), 27. 10.14233/ajchem.2013.11685

    Article  CAS  Google Scholar 

  14. Handbuch der präparativen anorganischen Chemie / Ed. G. Brauer. Stuttgart: Ferdinand Enke, 1981, Vol. 3, 1653.

  15. S. K. Dedushenko, L. N. Kholodkovskaya, Yu. D. Perfiliev, Yu. M. Kiselev, A. A. Saprykin, P. N. Komozin, and D. G. Lemesheva. J. Alloys Compd., 1997, 262, 78. 10.1016/S0925-8388(97)00332-0

    Article  CAS  Google Scholar 

  16. V. I. Goldanskii, A. V. Dolenko, B. G. Egizarov, V. P. Romashko, and A. I. Shamov. Prib. Tekh. Eksp., 1970, 13(4), 101. [In Russian]

  17. D. M. Levin and S. K. Dedushenko. Happy Sloth. Register of computer programs, 2016, 2016660090. www.happysloth.ru

  18. D. A. Shirley. Phys. Rev. B, 1972, 5, 4709. https://doi.org/10.1103/PhysRevB.5.4709

    Article  Google Scholar 

  19. S. K. Dedushenko, Yu. D. Perfiliev, M. G. Goldfeld, and A. I. Tsapin. Hyperfine Interact., 2001, 136/137, 373. 10.1023/A:1020541910373

    Article  CAS  Google Scholar 

  20. R. J. Audette, J. W. Quail, W. H. Black, and B. E. Robertson. J. Solid State Chem., 1973, 8, 43. https://doi.org/10.1016/0022-4596(73)90019-4

    Article  Google Scholar 

  21. A. D. Panov. Paket programm obrabotki spektrov SPRO i yazyk programmirovaniya SL (SPRO Spectrum Processing Package and SL Programming Language): Preprint 6019/15. Novosibirsk, Russia: Institute of Automation and Electrometry, 1997.

  22. M. I. Sosulnikov and Yu. A. Teterin. J. Electron. Spectrosc. Relat. Phenom., 1992, 59, 111. 10.1016/0368-2048(92)85002-O

    Article  CAS  Google Scholar 

  23. A. P. Grosvenor, B. A. Kobe, M. C. Biesinger, and N. S. McIntyre. Surf. Interface Anal., 2004, 36, 1564. https://doi.org/10.1002/sia.1984

    Article  CAS  Google Scholar 

  24. M. Descostes, F. Mercier, N. Thromat, C. Beaucaire, and M. Gautier-Soyer. Appl. Surf. Sci., 2000, 165, 288. https://doi.org/10.1016/S0169-4332(00)00443-8

    Article  CAS  Google Scholar 

  25. K. I. Maslakov, Y. A. Teterin, M. V. Ryzhkov, A. J. Popel, A. Y. Teterin, K. E. Ivanov, S. N. Kalmykov, V. G. Petrov, P. K. Petrov, and I. Farnan. Phys. Chem. Chem. Phys., 2018, 20, 16167. https://doi.org/10.1039/c8cp01442f

    Article  CAS  PubMed  Google Scholar 

  26. I. M. Band, Yu. I. Kharitonov, and M. B. Trzhaskovskaya. Atom Data Nucl. Data Tables, 1979, 23, 443. https://doi.org/10.1016/0092-640X(79)90023-8

    Article  CAS  Google Scholar 

  27. G. Wendin. Breakdown of the One-Electron Pictures in Photoelectron Spectra: Structure and Bonding, Vol. 45. Berlin, Heidelberg: Springer, 1981. https://doi.org/10.1007/BFb0111503

    Book  Google Scholar 

  28. J. H. Van Vleck. Phys. Rev., 1934, 45(5), 405. https://doi.org/10.1103/PhysRev.45.405

    Article  CAS  Google Scholar 

  29. A. G. Kochur, T. M. Ivanova, A. V. Shchukarev, R. V. Linko, A. A. Sidorov, M. A. Kiskin, V. M. Novotortsev, and I. L. Eremenko. J. Electron. Spectrosc. Relat. Phenom., 2010, 180, 21. https://doi.org/10.1016/j.elspec.2010.03.011

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Faculty of Chemistry, Moscow State University, Moscow, Russia

    Yu. A. Teterin, Yu. D. Perfil’ev & K. I. Maslakov

  2. National Research Center “Kurchatov Institute”, Moscow, Russia

    Yu. A. Teterin, A. Yu. Teterin, K. E. Ivanov & S. K. Dedushenko

  3. илиации:, Moscow, Russia

    V. G. Yarzhemskii

Authors
  1. Yu. A. Teterin
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Yu. D. Perfil’ev
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. K. I. Maslakov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. V. G. Yarzhemskii
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. A. Yu. Teterin
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. K. E. Ivanov
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. S. K. Dedushenko
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding authors

Correspondence to Yu. A. Teterin or S. K. Dedushenko.

Ethics declarations

The authors declare that they have no conflicts of interests.

Additional information

Russian Text © The Author(s), 2022, published in Zhurnal Strukturnoi Khimii, 2022, Vol. 63, No. 10, 99693.https://doi.org/10.26902/JSC_id99693

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Teterin, Y.A., Perfil’ev, Y.D., Maslakov, K.I. et al. STRUCTURE OF XPS SPECTRA OF K2FeO4. J Struct Chem 63, 1649–1661 (2022). https://doi.org/10.1134/S0022476622100110

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0022476622100110

Keywords

Search

Navigation