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SYNTHESES OF COBALT AND NICKEL COORDINATION POLYMERS COMPOSED OF 1,3-ADAMANTANEDICARBOXYLATE AND BIS(4-(1H-IMIDAZOL-1-YL)PHENYL) METHANONE LIGANDS

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Abstract

Two coordination polymers, {[Co2(L1)2(adc)2]·5H2O}n (1) and {[Ni(L1)2(Hadc)2]}n (2) (L1 = bis(4-(1H-imidazol-1-yl)phenyl)methanone, H2adc = adamantane-1,3-dicarboxylic acid), have been synthesized and structurally characterized. In 1, Co1 is five-coordinated by three oxygen atoms of two adc2– and two nitrogen atoms from two L1 ligands. The neighboring [Co(adc)]2 dimers are linked through four L1 ligands to form a 1D ladder structure. In 2, Ni1 is six-coordinated by two oxygen atoms from two Hadc– ligands, four nitrogen atoms from four distinct L1 ligands to give a slight distorted octahedral geometry. The [Ni(Hadc)2] units are bridged by L1 ligands to form 1D looped chains.

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Authors and Affiliations

  1. Department of Applied Chemistry, Yuncheng University, Yuncheng, People’s Republic of China

    G. -F. Wang & S. -W. Sun

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  1. G. -F. Wang
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  2. S. -W. Sun
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Text © The Author(s), 2022, published in Zhurnal Strukturnoi Khimii, 2022, Vol. 63, No. 10, 99360.https://doi.org/10.26902/JSC_id99360

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Wang, G.F., Sun, S.W. SYNTHESES OF COBALT AND NICKEL COORDINATION POLYMERS COMPOSED OF 1,3-ADAMANTANEDICARBOXYLATE AND BIS(4-(1H-IMIDAZOL-1-YL)PHENYL) METHANONE LIGANDS. J Struct Chem 63, 1610–1615 (2022). https://doi.org/10.1134/S0022476622100079

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