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MONONUCLEAR COMPLEXES OF Mn(II) AND Co(II) WITH FERROCENECARBOXYLIC ACID

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Abstract

Mononuclear coordination complexes of Mn(II) and Co(II) with ferrocenecarboxylic acid (FcCOOH) with the composition (NBu4)2[M(FcCOO)3(H2O)2)](FcCOO) are prepared. The XRD study showed that the distorted octahedral environment of the metal atom is formed by oxygen atoms of two water molecules and three FcCOO– anions in such a way that two anions are monodentate coordinated and one anion is bidentate-cyclic. The fourth anion is H-bonded with coordinated water molecules. Negatively charged {[M(FcCOO)3(H2O)2)](FcCOO)}– fragments, containing a new type of mononuclear transition metal carboxylate complex, are separated by tetrabutylammonium cations.

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Funding

The study was funded by the Russian Science Foundation, project No. 18-13-00380.

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Authors and Affiliations

  1. International Tomography Center, Siberian Branch, Russian Academy of Scienses, Novosibirsk, Russia

    G. V. Romanenko, S. E. Tolstikov, E. Yu. Fursova & V. I. Ovcharenko

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  1. G. V. Romanenko
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  2. S. E. Tolstikov
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  3. E. Yu. Fursova
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  4. V. I. Ovcharenko
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Correspondence to G. V. Romanenko.

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The authors declare that they have no conflicts of interests.

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Russian Text © The Author(s), 2022, published in Zhurnal Strukturnoi Khimii, 2022, Vol. 63, No. 10, 99181.https://doi.org/10.26902/JSC_id99181

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Romanenko, G.V., Tolstikov, S.E., Fursova, E.Y. et al. MONONUCLEAR COMPLEXES OF Mn(II) AND Co(II) WITH FERROCENECARBOXYLIC ACID. J Struct Chem 63, 1579–1583 (2022). https://doi.org/10.1134/S0022476622100043

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  • DOI: https://doi.org/10.1134/S0022476622100043

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