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REACTIVITY OF 16-ELECTRON (p-CYMENE)Ru HALF-SANDWICH COMPLEX CONTAINING A CHELATING 1,2-DICARBA-CLOSO- DODECABORANE-1,2-DITHIOLATE LIGAND WITH 1-ETHYNYL-1-CYCLOHEXANOL

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Abstract

The reaction of 16-electron complex (p-cymene)Ru(S2C2B10H10) (I) with (cyclo-C6H10)(OH)C≡CH in CH2Cl2 at —10 °C leads to a new complex (p-cymene)Ru(S2C2B10H9)(CH2C(OH)(cyclo-C6H10)) (II), which spontaneously lose water to generate complex (p-cymene)Ru(S2C2B10H9)(CH2C(cyclo-C6H9)) (III) in CH2Cl2 at room temperature. Both complexes were characterized by elemental analysis, mass, IR and NMR spectroscopy. X-ray structural analysis was performed on III. For complex III crystallographic data are: space group P21/c, a = 10.9787(11) Å, b = 14.5241(15) Å, c = 17.1028(17) Å, α = 90°, β = 107.8030(10)°, γ = 90°, V = 2596.5(5) Å3, Dc = 1.401 g/cm3, Z = 4, F(000) = 1176, μ = 0.774 mm–1. In the structure, the coordinated terminal alkyne is bonded to one of the Ru–S bonds, B-substitution occurs at the o-carborane cage in the position B(3) with the formation of Ru–B bond, and the central ruthenium atom bonded to a p-cymene ring satisfies the 18-electron rule.

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Authors and Affiliations

  1. College of Advanced Materials Engineering, Jiaxing Nanhu University, Zhejiang, People’s Republic of China

    J. R. Hu

  2. College of Humanities and Arts, Jiaxing Nanhu University, Zhejiang, People’s Republic of China

    J. H. Wang

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  1. J. R. Hu
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  2. J. H. Wang
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Text © The Author(s), 2022, published in Zhurnal Strukturnoi Khimii, 2022, Vol. 63, No. 10, 98943.https://doi.org/10.26902/JSC_id98943

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Hu, J.R., Wang, J.H. REACTIVITY OF 16-ELECTRON (p-CYMENE)Ru HALF-SANDWICH COMPLEX CONTAINING A CHELATING 1,2-DICARBA-CLOSO- DODECABORANE-1,2-DITHIOLATE LIGAND WITH 1-ETHYNYL-1-CYCLOHEXANOL. J Struct Chem 63, 1551–1557 (2022). https://doi.org/10.1134/S0022476622100018

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