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TUNGSTEN PEROXOPOLYOXO COMPLEXES– PROMISING CATALYSTS FOR OXIDATION OF ORGANIC COMPOUNDS. II. STRUCTURE OF THE [(n-Oct)3NME]3{PO4[WO(O2)2]4} COMPLEX FROM THE SMALL-ANGLE X-RAY SCATTERING DATA

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Abstract

By small angle X-ray scattering (SAXS) solutions of the [(n-Oct)3NMe]3{PO4[WO(O2)2]4} peroxopolyoxo complex are studied using 13 different organic solvents. In solutions of heptane, cyclohexane, and diethyl ether, the peroxo complex is shown to form large aggregates. In a number of other solvents tested, the complex is present as individual molecules in the solution. The size of the molecules is 14.5±1.2 Å. Structural parameters of the complex are found, and a low resolution model of the structure is proposed.

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Funding

The work was supported by RFBR (project No. 19-03-00202а) and the state assignment for the Institute of Catalysis, Siberian Branch, Russian Academy of Sciences (projects Nos. АААА-А21-121011390007-7 and АААА-А21-121011390053-4).

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Authors and Affiliations

  1. Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    Yu. V. Larichev, N. V. Selivanova, P. V. Berdnikova & Z. P. Pai

  2. Novosibirsk State University, Novosibirsk, Russia

    Yu. V. Larichev

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  1. Yu. V. Larichev
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  2. N. V. Selivanova
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  3. P. V. Berdnikova
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Correspondence to Yu. V. Larichev.

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Russian Text © The Author(s), 2022, published in Zhurnal Strukturnoi Khimii, 2022, Vol. 63, No. 8, 95215.https://doi.org/10.26902/JSC_id95215

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Larichev, Y.V., Selivanova, N.V., Berdnikova, P.V. et al. TUNGSTEN PEROXOPOLYOXO COMPLEXES– PROMISING CATALYSTS FOR OXIDATION OF ORGANIC COMPOUNDS. II. STRUCTURE OF THE [(n-Oct)3NME]3{PO4[WO(O2)2]4} COMPLEX FROM THE SMALL-ANGLE X-RAY SCATTERING DATA. J Struct Chem 63, 1215–1223 (2022). https://doi.org/10.1134/S0022476622080029

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