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SYNTHESIS AND CRYSTAL STRUCTURE OF CsLnZnS3 (Ln = Gd, Dy)

Abstract

CsLnZnS3 (Ln = Gd, Dy) crystals are obtained by the interaction of metal sulfides in the cesium iodide melt. It is found that these compounds are isostructural, belong to the KCuZrS3 structure type, and crystallize in the space group Cmcm with the parameters a = 4.010(5) Å, b = 15.32(3) Å, c = 10.542(19) Å for CsGdZnS3 and a = 4.0106(3) Å, b = 15.2493(12) Å, c = 10.5978(8) Å for CsDyZnS3. The structures of these compounds consist of {LnS6} octahedra and {ZnS4} tetrahedra, which by sharing edges, form charged 2∞{LnZnS3} layers separated by Cs+ ions. Band gaps of these compounds are determined as 3.70 eV and 3.84 eV for CsGdZnS3 and CsDyZnS3 respectively.

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Funding

The work was supported by the Ministry of Science and Higher Education of the Russian Federation (projects Nos. 121031700315-2 and 121031700313-8).

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Correspondence to T. A. Pomelova.

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Park, S.C., Kuratieva, N.V., Pomelova, T.A. et al. SYNTHESIS AND CRYSTAL STRUCTURE OF CsLnZnS3 (Ln = Gd, Dy). J Struct Chem 63, 868–873 (2022). https://doi.org/10.1134/S0022476622060038

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  • DOI: https://doi.org/10.1134/S0022476622060038

Keywords

  • gadolinium
  • dysprosium
  • lanthanides
  • chalcogenides
  • synthesis
  • crystal structure.