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A FOUR-NUCLEAR Ag(I) COMPLEX SUPPORTED BY A N,N′,N″,P-LIGAND: SYNTHESIS, CRYSTAL AND ELECTRONIC STRUCTURE

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Abstract

A four-nuclear complex [Ag4(Lut3P)2(MeCN)2](BF4)4 is synthesized by treating tris[(6-methylpyridin-2-yl)methyl]phosphine (Lut3P) with AgBF4 in a MeCN solution. The crystal and electronic structure of the obtained complex are studied using X-ray diffraction analysis and DFT computations. Moreover, solid-state photoluminescence of the title compound is examined at ambient temperature.

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Funding

This work was supported by Russian Science Foundation (Project N 21-73-10110) and the Ministry of Science and Higher Education of the Russian Federation (Project N 121031700321-3). The authors are also grateful to Dr. Evgeniya Doronina (A. E. Favorsky Irkutsk Institute of Chemistry, Russia) for performing DFT calculations.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    U. A. Lapteva, A. Yu. Baranov, D. G. Samsonenko & A. V. Artem′ev

  2. Department of Natural Sciences, Novosibirsk State University, (National Research University), Novosibirsk, Russia

    U. A. Lapteva

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  1. U. A. Lapteva
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  2. A. Yu. Baranov
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  3. D. G. Samsonenko
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  4. A. V. Artem′ev
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Correspondence to A. V. Artem′ev.

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Text © The Author(s), 2022, published in Zhurnal Strukturnoi Khimii, 2022, Vol. 63, No. 4, pp. 527-529.https://doi.org/10.26902/JSC_id95901

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Lapteva, U.A., Baranov, A.Y., Samsonenko, D.G. et al. A FOUR-NUCLEAR Ag(I) COMPLEX SUPPORTED BY A N,N′,N″,P-LIGAND: SYNTHESIS, CRYSTAL AND ELECTRONIC STRUCTURE. J Struct Chem 63, 663–668 (2022). https://doi.org/10.1134/S0022476622040199

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