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SUPRAMOLECULAR ASSEMBLIES IN AN UNPRECEDENTED ASYMMETRIC SALAMO-BASED DINUCLEAR NICKEL(II) COMPLEX BEARING TWO DIFFERENT COORDINATION MODES

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Abstract

An unprecedented dinuclear Ni(II) complex [{Ni2(L)(HL)(μ-OAc)(H2O)}2]·3CH3CH2OH is successfully synthesized by the complexation of an asymmetric salamo-based ligand (H2L) and Ni(II) acetate tetrahydrate and characterized by elemental analyses, UV-Vis and IR spectra, and X-ray crystallography analyses. Surprisingly, in the asymmetric unit of the Ni(II) complex, a fully deprotonated ligand (L)2– unit and a partially deprotonated ligand (HL)– unit wrapps two Ni(II) atoms, with the μ-OAc– anion bridging two adjacent Ni(II) atoms. The two Ni(II) atoms possess different coordination environments and twisted octahedral geometries. The hexacoordinated Ni(II) atom (Ni1) is located in the N2O4 donor cavity, but another hexacoordinated Ni(II) atom (Ni2) is located in a NO5 donor coordination environment. Meanwhile, a1D chain structure is formed by two N–O⋯π interactions. Hirshfeld surfaces and fluorescent properties are investigated.

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This work was supported by the National Natural Science Foundation of China (21761018), which is gratefully acknowledged.

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  1. School of Chemistry and Chemical Engineering, Lanzhou Jiaotong University, Lanzhou, People’s Republic of China

    M. Li, L. -L. Li, P. Li & W. -K. Dong

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  1. M. Li
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  2. L. -L. Li
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Text © The Author(s), 2022, published in Zhurnal Strukturnoi Khimii, 2022, Vol. 63, No. 2, pp. 220-223.https://doi.org/10.26902/JSC_id88419

The original online version of this article was revised: Modification has been made to the Graphical Abstract. Full information regarding the corrections made can be found in the erratum for this article.

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Li, M., Li, L.L., Li, P. et al. SUPRAMOLECULAR ASSEMBLIES IN AN UNPRECEDENTED ASYMMETRIC SALAMO-BASED DINUCLEAR NICKEL(II) COMPLEX BEARING TWO DIFFERENT COORDINATION MODES. J Struct Chem 63, 280–292 (2022). https://doi.org/10.1134/S0022476622020093

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