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SYNTHESIS AND STRUCTURES OF COORDINATION POLYMERS BASED ON A BRIDGING LIGAND WITH THE THIENOTHIOPHENE BACKBONE

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Abstract

Two novel metal-organic coordination polymers [Sr(ttdc)(dma)2] (1) and [Zn(ttdc)(bpy)]·DMA·4H2O (2) (H2ttdc = thieno[3,2-b]thiophene-2,5-dicarboxylic acid, bpy = 2,2′-bipyridyl, DMA = N,N-dimethylacetamide) are synthesized under solvothermal conditions. Structures of the compounds are established by the single crystal X-ray diffraction (XRD) analysis. The coordination polymers are characterized by powder XRD, elemental and thermogravimetric analyses, and IR spectroscopy. Compound 1 is a 2D coordination polymer while compound 2 is composed of zigzag chains linked by π–π stacking between bpy molecules into a porous supramolecular framework with a free volume of 42%.

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Funding

The work was supported by the Russian Science Foundation (grant No. 18-13-00203, https://rscf.ru/project/18-13-00203/) and the Ministry of Science and Higher Education of the Russian Federation (project No. 121031700321-3).

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    V. A. Dubskikh, A. A. Lysova, D. G. Samsonenko, D. N. Dybtsev & V. P. Fedin

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  1. V. A. Dubskikh
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  2. A. A. Lysova
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  3. D. G. Samsonenko
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  4. D. N. Dybtsev
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  5. V. P. Fedin
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Corresponding author

Correspondence to V. P. Fedin.

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Russian Text © The Author(s), 2022, published in Zhurnal Strukturnoi Khimii, 2022, Vol. 63, No. 2, pp. 163-170.https://doi.org/10.26902/JSC_id87114

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Dubskikh, V.A., Lysova, A.A., Samsonenko, D.G. et al. SYNTHESIS AND STRUCTURES OF COORDINATION POLYMERS BASED ON A BRIDGING LIGAND WITH THE THIENOTHIOPHENE BACKBONE. J Struct Chem 63, 227–234 (2022). https://doi.org/10.1134/S0022476622020032

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