Skip to main content
SpringerLink
Log in

MAGNETIC ANOMALIES IN POLYMERIC CHAIN COMPLEXES Cu(hfac)2 WITH SPIN-LABELED DIALKYLPYRAZOLES

  • Published:
Journal of Structural Chemistry Aims and scope Submit manuscript

Abstract

The structures of hexafluoroacetylacetonate complexes of Cu(II)–Cu(hfac)2– with nitroxide radicals LR1/R2, where R1 and R2 are alkyl substituents in the 1,3-pyrazole moiety are studied by X-ray crystallography. It is found that solid phases of all [Cu(hfac)2LR1/R2] are formed by polymeric chains whose common structural motif is a ditopic bridging coordination of paramagnetic ligands in the head-to-head fashion. The study of the temperature structure dynamics and the related change in the temperature dependence of the effective magnetic moment of the complex shows that changes in both R1 and R2 can substantially affect not only the possibility of the appearance of magnetic anomalies on the temperature curve of the effective magnetic moment but also its shape.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Scheme 1
Scheme 2
Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8

Similar content being viewed by others

REFERENCES

  1. V. Ovcharenko. In: Stable Radicals / Ed. R. Hicks. Chichester, UK: John Wiley & Sons, Ltd, 2010, 461-506. https://doi.org/10.1002/9780470666975.ch13

    Article  Google Scholar 

  2. V. Ovcharenko and E. Bagryanskaya. In: Spin-Crossover Mater / Ed. M. A. Halcrow. Oxford, UK: John Wiley & Sons Ltd, 2013, 239-280. https://doi.org/10.1002/9781118519301.ch9

    Article  Google Scholar 

  3. N. A. Artiukhova, G. V. Romanenko, A. S. Bogomyakov, I. Y. Barskaya, S. L. Veber, M. V. Fedin, K. Y. Maryunina, K. Inoue, and V. I. Ovcharenko. J. Mater. Chem. C, 2016, 4, 11157-11163. https://doi.org/10.1039/C6TC03216H

    Article  CAS  Google Scholar 

  4. S. V. Fokin, E. T. Kostina, E. V. Tretyakov, G. V. Romanenko, A. S. Bogomyakov, R. Z. Sagdeev, and V. I. Ovcharenko. Russ. Chem. Bull., 2013, 62, 661-671. https://doi.org/10.1007/s11172-013-0089-y

    Article  CAS  Google Scholar 

  5. S. E. Tolstikov, N. A. Artiukhova, G. V. Romanenko, A. S. Bogomyakov, E. M. Zueva, I. Y. Barskaya, M. V. Fedin, K. Y. Maryunina, E. V. Tretyakov, R. Z. Sagdeev, and V. I. Ovcharenko. Polyhedron, 2015, 100, 132-138. https://doi.org/10.1016/j.poly.2015.07.029

    Article  CAS  Google Scholar 

  6. V. I. Ovcharenko, S. V. Fokin, E. T. Kostina, G. V. Romanenko, A. S. Bogomyakov, and E. V. Tretyakov. Inorg. Chem., 2012, 51, 12188-12194. https://doi.org/10.1021/ic301328x

    Article  CAS  PubMed  Google Scholar 

  7. V. Ovcharenko, S. Fokin, E. Chubakova, G. Romanenko, A. Bogomyakov, Z. Dobrokhotova, N. Lukzen, V. Morozov, M. Petrova, M. Petrova, G. Levkovskaya, and R. Sagdeev. Inorg. Chem., 2016, 55, 5853-5861. https://doi.org/10.1021/acs.inorgchem.6b00140

    Article  CAS  PubMed  Google Scholar 

  8. K. Y. Maryunina, X. Zhang, S. Nishihara, K. Inoue, V. A. Morozov, G. V. Romanenko, and V. I. Ovcharenko. J. Mater. Chem. C, 2015, 3, 7788-7791. https://doi.org/10.1039/C5TC01005E

    Article  CAS  Google Scholar 

  9. V. Ovcharenko, G. Romanenko, A. Polushkin, G. Letyagin, A. Bogomyakov, M. Fedin, K. Maryunina, S. Nishihara, K. Inoue, M. Petrova, V. Morozov, and E. Zueva. Inorg. Chem., 2019, 58, 9187-9194. https://doi.org/10.1021/acs.inorgchem.9b00815

    Article  CAS  PubMed  Google Scholar 

  10. E. T. Chubakova. Sintez, stroenie i svoistva geyerospinovykh kompleksov bis(geksaftoratsetilatsetonato) medi(II) s novymi pirazolil-zameshchennymi nitroksil’nymi radikalami (Synthesis, Structure, and Properties of Heterospin Complexes of bis(Hexafluoroacetylacetonato) Copper(II) with New Pyrasolyl-Substituted Nitroxide Radicals): Cand. (Chem.) Dissertation. Novosibirsk: Nikolaev Institute of Inorganic Chemistry, 2014. [In Russian]

  11. V. I. Ovcharenko, S. V. Fokin, G. V. Romanenko, I. V. Korobkov, and P. Rey. Russ. Chem. Bull., 1999, 48, 1519-1525. https://doi.org/10.1007/BF02496404

    Article  CAS  Google Scholar 

  12. G. V. Romanenko, S. V. Fokin, S. F. Vasilevskii, E. V. Tretyakov, Y. G. Shvedenkov, and V. I. Ovcharenko. Russ. J. Coord. Chem., 2001, 27, 360-367. https://doi.org/10.1023/A:1011354314831

    Article  CAS  Google Scholar 

  13. V. Ovcharenko, S. Fokin, E. Chubakova, G. Romanenko, A. Bogomyakov, Z. Dobrokhotova, N. Lukzen, V. Morozov, M. M. Petrova, M. M. Petrova, E. Zueva, I. Rozentsveig, E. Rudyakova, G. Levkovskaya, and R. Sagdeev. Inorg. Chem., 2016, 55, 5853-5861. https://doi.org/10.1021/acs.inorgchem.6b00140

    Article  CAS  PubMed  Google Scholar 

  14. G. M. Sheldrick. Acta Crystallogr., Sect. A: Found. Adv., 2015, 71, 3-8. https://doi.org/10.1107/S2053273314026370

    Article  Google Scholar 

  15. G. M. Sheldrick. Acta Crystallogr., Sect. C: Struct. Chem., 2015, 71, 3-8. https://doi.org/10.1107/S2053229614024218

    Article  Google Scholar 

  16. E. V. Tretyakov and V. I. Ovcharenko. Russ. Chem. Rev., 2009, 78, 971-1012. https://doi.org/10.1070/RC2009v078n11ABEH004093

    Article  CAS  Google Scholar 

  17. C. R. Groom, I. J. Bruno, M. P. Lightfoot, and S. C. Ward. Acta Crystallogr., Sect. B: Struct. Sci. Cryst. Eng. Mater., 2016, 72, 171-179. https://doi.org/10.1107/S2052520616003954

    Article  CAS  Google Scholar 

  18. S. Fokin, V. Ovcharenko, G. Romanenko, and V. Ikorskii. Inorg. Chem., 2004, 43, 969-977. https://doi.org/10.1021/ic034964d

    Article  CAS  PubMed  Google Scholar 

  19. E. M. Zueva, E. R. Ryabykh, and A. M. Kuznetsov. Russ. Chem. Bull., 2009, 58, 1654-1662. https://doi.org/10.1007/s11172-009-0228-7

    Article  CAS  Google Scholar 

  20. V. I. Ovcharenko, G. V. Romanenko, K. Y. Maryunina, A. S. Bogomyakov, and E. V. Gorelik. Inorg. Chem., 2008, 47, 9537-9552. https://doi.org/10.1021/ic8011074

    Article  CAS  PubMed  Google Scholar 

  21. V. A. Morozov, M. V. Petrova, and N. N. Lukzen. AIP Adv., 2015, 5, 087161. https://doi.org/10.1063/1.4929526

    Article  CAS  Google Scholar 

Download references

Funding

The work was supported by the Russian Science Foundation (grant No.17-13-01022) and RFBR in the synthesis of the compounds (grant No. 18-29-04002).

Author information

Authors and Affiliations

  1. Institute “International Tomography Center”, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    G. V. Romanenko, S. V. Fokin, E. T. Chubakova, A. S. Bogomyakov & V. I. Ovcharenko

  2. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russia

    A. S. Bogomyakov & V. I. Ovcharenko

Authors
  1. G. V. Romanenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. S. V. Fokin
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. E. T. Chubakova
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. A. S. Bogomyakov
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. V. I. Ovcharenko
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to V. I. Ovcharenko.

Ethics declarations

The authors declare that they have no conflict of interests.

Additional information

Russian Text © The Author(s), 2022, published in Zhurnal Strukturnoi Khimii, 2022, Vol. 63, No. 1, pp. 48-60.https://doi.org/10.26902/JSC_id85865

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Romanenko, G.V., Fokin, S.V., Chubakova, E.T. et al. MAGNETIC ANOMALIES IN POLYMERIC CHAIN COMPLEXES Cu(hfac)2 WITH SPIN-LABELED DIALKYLPYRAZOLES. J Struct Chem 63, 87–99 (2022). https://doi.org/10.1134/S0022476622010103

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0022476622010103

Keywords

Search

Navigation