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A COPPER(I) COORDINATION COMPOUND WITH RED PHOTOLUMINESCENCE

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Abstract

Peculiar coordination compound Cu(Hbpt)(CH3CN)2PF6 (1) derived from 3,5-bis(4-pyridyl)-1H-1,2,4-triazole (Hbpt) is synthesized by the layer diffusion method and structurally characterized by single crystal and powder X-ray diffraction, elemental analysis, and infrared spectroscopy. Compound 1 exhibits a structure formed by cationic \([\text{Cu}(\text{Hbpt}){{(\text{C}{{\text{H}}_{\text{3}}}\text{CN})}_{\text{2}}}]_{n}^{n+}\) chains and \(\text{PF}_{6}^{-}\) anions with abundant supramolecular interactions. Solid-state photoluminescence experiments show that compound 1 exhibits relatively strong red emission with a peak around 656 nm, and the origin of the emission band may be ascribed to the metal-to-ligand charge transfer according to the calculation of the density of states.

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Funding

We gratefully acknowledge the financial support of the National Natural Science Foundation of China (21071156) and the Natural Science Foundation of Chongqing (cstc2019jcyj-msxmX0170) and the National College Student′s Innovative Entrepreneurship Iraining Program (202110637007).

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Authors and Affiliations

  1. Chongqing Key Laboratory of Green Synthesis and Applications, College of Chemistry, Chongqing Normal University, Chongqing, People’s Republic of China

    Y. -L. Tao, C. -H. Wang, H. -Y. Xiang, G. -R. Li, C. -H. Li & X. Liu

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  1. Y. -L. Tao
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  2. C. -H. Wang
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  3. H. -Y. Xiang
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  4. G. -R. Li
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  5. C. -H. Li
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  6. X. Liu
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Correspondence to X. Liu.

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Russian Text © The Author(s), 2022, published in Zhurnal Strukturnoi Khimii, 2022, Vol. 63, No. 1, pp. 5-7.https://doi.org/10.26902/JSC_id84800

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Tao, Y.L., Wang, C.H., Xiang, H.Y. et al. A COPPER(I) COORDINATION COMPOUND WITH RED PHOTOLUMINESCENCE. J Struct Chem 63, 1–8 (2022). https://doi.org/10.1134/S0022476622010012

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  • DOI: https://doi.org/10.1134/S0022476622010012

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