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SYNTHESIS AND STRUCTURE OF TRIARYLBISMUTH bis(2,3-DIFLUOROBENZOATES)

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Abstract

Triarylbismuth dicarboxylates p-Tol3Bi[OC(O)C6H3F2-2,3]2 (1) and m-Tol3Bi[OC(O)C6H3F2-2,3]2 (2) are synthesized by the oxidative addition reaction between triarylbismuth and 2,3-difluorobenzoic acid in the presence of tert-butyl peroxide. According to single crystal X-ray diffraction data, bismuth atoms have the coordination of a distorted trigonal bipyramid with oxygen atoms of carboxylate ligands in axial positions. Axial OBiO angles are 171.09(12)° (1) and 173.50(9)° (2). Lengths of Bi–C bonds have close values: 2.198(5)-2.213(4) Å in 1 and 2.165(3)-2.195(5) Å in 2. The Bi–O lengths (2.261(3) Å, 2.306(3) Å in 1 and 2.284(3) Å, 2.243(3) Å in 2) are comparable with the lengths of Bi–O covalent bonds. The bismuth atom is out of the [С3] equatorial plane by 0.007 Å and 0.012 Å in 1 and 2 respectively. The Bi⋯O=C distances are 2.878(5) Å, 2.953(4) Å (1) and 2.891(3) Å, 3.056(4) Å (2), which is much smaller than the sum of Van der Waals radii of Bi and O atoms of 3.9 Å. The formation of the spatial structure of the crystals of compounds 1 and 2 is governed by the occurrence of С=О⋯H, С(Ar)–Н⋯F hydrogen bonds, СН⋯π interactions, and the stacking effect.

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  1. Southern Ural State University, Chelyabinsk, Russia

    A. N. Efremov, V. V. Sharutin & O. K. Sharutina

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  1. A. N. Efremov
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Russian Text © The Author(s), 2021, published in Zhurnal Strukturnoi Khimii, 2021, Vol. 62, No. 12, pp. 2084-2090.https://doi.org/10.26902/JSC_id84811

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Efremov, A.N., Sharutin, V.V. & Sharutina, O.K. SYNTHESIS AND STRUCTURE OF TRIARYLBISMUTH bis(2,3-DIFLUOROBENZOATES). J Struct Chem 62, 1962–1968 (2021). https://doi.org/10.1134/S0022476621120155

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