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TWO Zn(II)/Cu(II) COMPLEXES BASED ON FLEXIBLE MIXED LIGANDS: SYNTHESES, STRUCTURAL CHARACTERIZATION, AND LUMINESCENCE SENSING OF NITROBENZENE

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Abstract

Two Zn(II) and Cu(II) complexes formulated as Zn(DMS)(bix)0.5 (1) and Cu(DMS)(bix)0.5 (2) (DMS = 2,2-dimethylsuccinate; bix = 1,4-bis(imidazol-1-ylmethyl)benzene) are successfully prepared under hydrothermal conditions. The single crystal X-ray diffraction (XRD) analysis shows that both complexes are isostructural, have the P2/c space group and a 2D layer architecture with the DMS bisbridged ribbon. The title complexes are characterized by single crystal XRD, IR spectroscopy, TG and elemental analyses, and photoluminescence sensing in the solid state. In addition, the sensing efficiency of nitrobenzene for 1 is evaluated.

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Authors and Affiliations

  1. Key Laboratory of Functional Organometallic Materials, College of Chemistry and Materials Science, Hengyang Normal University, Hengyang City, Hunan Province, People’s Republic of China

    Y. Liu, W. Li, Y. -Q. Yang, M. -S. Chen & W. -W. Fu

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  1. Y. Liu
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  2. W. Li
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  3. Y. -Q. Yang
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  4. M. -S. Chen
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  5. W. -W. Fu
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Correspondence to Y. Liu.

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Russian Text © The Author(s), 2021, published in Zhurnal Strukturnoi Khimii, 2021, Vol. 62, No. 12, pp. 2077-2083.https://doi.org/10.26902/JSC_id84806

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Liu, Y., Li, W., Yang, Y.Q. et al. TWO Zn(II)/Cu(II) COMPLEXES BASED ON FLEXIBLE MIXED LIGANDS: SYNTHESES, STRUCTURAL CHARACTERIZATION, AND LUMINESCENCE SENSING OF NITROBENZENE. J Struct Chem 62, 1955–1961 (2021). https://doi.org/10.1134/S0022476621120143

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