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CRYSTAL CHEMISTRY OF NOVEL “ANTIZEOLITE” STRUCTURES

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Abstract

The “antizeolite” concept, which was originally proposed for mayenite-type structures, can also be successfully applied to a number of compounds containing large cations and characterized by a conservative cationic “framework” with cavities, some of which can contain disordered and very diverse anionic clusters, similarly to the zeolite anionic frameworks whose large cavities contain variable cationic ensembles. This approach and its use to control the functional properties of corresponding materials are considered on the example of recently described novel “antizeolite” structural types such as barium orthoborate Ba3(BO3)2 and burbankite Na2Ca4(CO3)5.

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Funding

The reported study was funded by the Russian Science Foundation, project No. 21-19-00097.

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Authors and Affiliations

  1. Sobolev Institute of Geology and Mineralogy, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    S. V. Rashchenko & T. B. Bekker

  2. Novosibirsk State University, Novosibirsk, Russia

    S. V. Rashchenko & T. B. Bekker

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  1. S. V. Rashchenko
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Correspondence to S. V. Rashchenko.

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Russian Text © The Author(s), 2021, published in Zhurnal Strukturnoi Khimii, 2021, Vol. 62, No. 12, pp. 2057-2067.https://doi.org/10.26902/JSC_id84794

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Rashchenko, S.V., Bekker, T.B. CRYSTAL CHEMISTRY OF NOVEL “ANTIZEOLITE” STRUCTURES. J Struct Chem 62, 1935–1945 (2021). https://doi.org/10.1134/S002247662112012X

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