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STRUCTURES AND THERMAL PROPERTIES OF SILVER(I) β-DIKETONATES WITH BULKY TERMINAL SUBSTITUENTS

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Abstract

Silver β-diketonates [Ag(RC(O)CHC(O)R′)]∞ with bulky terminal substituents are synthesized and characterized: R = C(OCH3)(CH3)2, R′ = CF3 (1), R = R′ = C(CH3)3 (2). Complex 1 is obtained for the first time. Structures of compounds are determined by single crystal X-ray diffraction. For complex 1 the crystallographic data are: space group \(P\bar{1}\), a = 5.8012(6) Å, b = 9.1717(10) Å, c = 9.9251(11) Å, α = 73.722(4)°, β = 78.377(4)°, γ = 87.336(4)°, V = 496.49(9) Å3, Z = 2, dcalc = 2.134 g/cm3, μ = 2.059 mm–1; for complex 2: space group C2, a = 22.1700(6) Å, b = 5.84530(10) Å, c = 9.3249(2) Å, β = 104.9670(10)°, V = 1167.42(5) Å3, Z = 4, dcalc = 1.656 g/cm3, μ = 1.701 mm–1. Both compounds are chain coordination polymers. Anions are coordinated in a bidentate-cyclic fashion. One of carbonyl oxygen atoms and the carbon atom in the CH-group perform the bridging function. In complex 2, the coordination environment of silver is a distorted vacant trigonal bipyramid (CN = 4). In complex 1, it is a tetragonal pyramid due to the additional coordination of the methoxy oxygen atom of the neighboring anion (CN = 5). The structure and thermal stability of the synthesized complexes are compared with those of the closest analogue (R = C(CH3)3, R′ = CF3), which allowed us to reveal the effect of terminal substituents in the β-diketonate ligand.

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Funding

The work was supported by grant MK-6148.2021.1.3 of the President of the Russian Federation for young scientists–candidates of science.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    S. A. Gulyaev, E. S. Vikulova, T. S. Sukhikh, I. Yu. Ilyin & N. B. Morozova

  2. Novosibirsk State University, Novosibirsk, Russia

    S. A. Gulyaev

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  1. S. A. Gulyaev
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  2. E. S. Vikulova
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  3. T. S. Sukhikh
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  4. I. Yu. Ilyin
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Correspondence to S. A. Gulyaev.

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Russian Text © The Author(s), 2021, published in Zhurnal Strukturnoi Khimii, 2021, Vol. 62, No. 12, pp. 1953-1962.https://doi.org/10.26902/JSC_id83846

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Gulyaev, S.A., Vikulova, E.S., Sukhikh, T.S. et al. STRUCTURES AND THERMAL PROPERTIES OF SILVER(I) β-DIKETONATES WITH BULKY TERMINAL SUBSTITUENTS. J Struct Chem 62, 1836–1845 (2021). https://doi.org/10.1134/S0022476621120039

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