Skip to main content
SpringerLink
Log in

CRYSTAL STRUCTURE OF La(III), Pr(III), AND Eu(III) COMPLEXES WITH A MACROCYCLIC CAVITAND CUCURBIT[6]URIL

  • Published:
Journal of Structural Chemistry Aims and scope Submit manuscript

Abstract

Complexes [La(H2O)3(DMF@C36H36N24O12)(NO3)](NO3)2·6H2O (1) and [M(H2O)3(DMF@C36H36N24O12) (HCOO)](NO3)2·6H2O (where M = Pr (2) and Eu (3)) are prepared and structurally characterized by XRD upon heating a mixture of aqueous nitrates La(III), Pr(III), and Eu(III), cucurbit[6]uril (C36H36N24O12), and DMF up to 100 °C. The metal atoms in the obtained complexes are coordinated by three oxygen atoms of the neighboring carbonyl groups of the macrocyclic cavitand. The lanthanum atoms are disordered, the alternative positions are related through a two-fold symmetry axis. The complexes have a 0D structure. The inner cavity of cucurbit[6]uril molecules is occupied by a DMF molecule, while the oxygen atom of the guest molecule coordinates the lanthanide atoms. The structures of crystals 1-3 contain H-bonded “directed chains”.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3

Similar content being viewed by others

REFERENCES

  1. W. A. Freeman. Acta Crystallogr., Sect. B, 1984, 40, 382. https://doi.org/10.1107/S0108768184002354

    Article  Google Scholar 

  2. J. Heo, J. Kim, D. Whang, and K. Kim. Inorg. Chim. Acta, 2000, 297, 307. https://doi.org/10.1016/S0020-1693(99)00318-7

    Article  CAS  Google Scholar 

  3. D. G. Samsonenko, A. A. Sharonova, M. N. Sokolov, A. V. Virovets, and V. P. Fedin. Russ. J. Coord. Chem., 2001, 27, 10. https://doi.org/10.1023/A:1009528522610

    Article  CAS  Google Scholar 

  4. O. A Gerasko, D. G Samsonenko, and V. P. Fedin. Russ. Chem. Rev., 2002, 71, 741. https://doi.org/10.1070/RC2002v071n09ABEH000748

    Article  CAS  Google Scholar 

  5. D. G. Samsonenko, J. Lipkowski, O. A. Gerasko, A. V. Virovets, M. N. Sokolov, V. P. Fedin, J. G. Platas, R. Hernandez-Molina, and A. Mederos. Eur. J. Inorg. Chem., 2002, 2380. https://doi.org/10.1002/1099-0682(200209)2002:9<2380::AID-EJIC2380>3.0.CO;2-2

    Article  Google Scholar 

  6. D. G. Samsonenko, M. N. Sokolov, O. A. Gerasko, A. V. Virovets, J. Lipkowski, D. Fenske, and V. P. Fedin. Russ. Chem. Bull., 2003, 52, 2131. https://doi.org/10.1023/B:RUCB.0000011868.74173.8d

    Article  CAS  Google Scholar 

  7. D. G. Samsonenko, O. A. Gerasko, J. Lipkowski, A. V. Virovets, and V. P. Fedin. Russ. Chem. Bull., 2002, 51, 1915. https://doi.org/10.1023/A:1021316921801

    Article  CAS  Google Scholar 

  8. A. A. Tripolskaya, E. A. Mainicheva, T. V. Mitkina, O. A. Gerasko, D. Yu. Naumov, and V. P. Fedin. Russ. Coord. Chem., 2005, 31, 768. https://doi.org/10.1007/s11173-005-0167-2

    Article  CAS  Google Scholar 

  9. A. A. Tripolskaya, O. A. Gerasko, D. Yu. Naumov, and V. P. Fedin. J. Struct. Chem., 2007, 48(5), 949. https://doi.org/10.1007/s10947-007-0139-0

    Article  CAS  Google Scholar 

  10. C.-Y. Shan, W.-X. Zhao, Z. Tao, and Y.-Q. Zhang. Inorg. Chem. Commun., 2016, 71, 109. https://doi.org/10.1016/j.inoche.2016.03.010

    Article  CAS  Google Scholar 

  11. W. A. Freeman, W. L. Mock, and N.-Y. Shih. J. Am. Chem. Soc., 1981, 103, 7367. https://doi.org/10.1021/ja00414a070

    Article  CAS  Google Scholar 

  12. NETZSCH Proteus Thermal Analysis v.4.8.1. Bayern, Germany: NETZSCH-Gerätebau, 2005.

  13. SADABS. Madison, Wisconsin, USA: Bruker Advanced X-ray Solutions, 2016.

  14. G. M. Sheldrick. Acta Crystallogr., Sect. A, 2015, 71, 3-8.

  15. G. M. Sheldrick. Acta Crystallogr., Sect. C, 2015, 71, 3-8.

  16. R.-L. Lin, J.-X. Liu, L.-S. Long, R.-B. Huang, and L.-S. Zheng. J. Inclusion Phenom. Macrocyclic Chem., 2008, 62, 263. https://doi.org/10.1007/s10847-008-9466-9

    Article  CAS  Google Scholar 

  17. D. G. Samsonenko, A. V. Virovets, Ya. Lipkovski, O. A. Gerasko, and V. P. Fedin. J. Struct. Chem., 2002, 43(4), 664. https://doi.org/10.1023/A:1022008822653

    Article  CAS  Google Scholar 

  18. E. A. Kovalenko, M. Yu. Palatkina, D. G. Samsonenko, and V. P. Fedin. Russ. J. Coord. Chem., 2012, 38, 379. https://doi.org/10.1134/S1070328412050041

    Article  CAS  Google Scholar 

  19. E. A. Kovalenko, D. G. Samsonenko, D. Yu. Naumov, and V. P. Fedin. Russ. Chem. Bull., 2014, 63, 64. https://doi.org/10.1007/s11172-014-0395-z

    Article  CAS  Google Scholar 

  20. E. A. Kovalenko, D. G. Samsonenko, D. Yu. Naumov, and V. P. Fedin. J. Struct. Chem., 2014, 55(8), 1448. https://doi.org/10.1134/S0022476614080113

    Article  CAS  Google Scholar 

  21. E. A. Kovalenko, D. Yu. Naumov, and V. P. Fedin. Polyhedron, 2018, 144, 158. https://doi.org/10.1016/j.poly.2018.01.021

    Article  CAS  Google Scholar 

  22. D. G. Samsonenko, M. N. Sokolov, O. A. Gerasko, A. V. Virovets, Ya. Likovski, D. Fenske, and V. P. Fedin. Russ. Chem. Bull., 2003, 52, 2132. https://doi.org/10.1023/B:RUCB.0000011868.74173.8d

    Article  CAS  Google Scholar 

  23. A. P. Souza, F. A. Almeida Paz, R. O. Freire, L. D. Carlos, O. L. Malta, S. Alves, and G. F. Sa. J. Phys. Chem. B, 2007, 111, 9228. https://doi.org/10.1021/jp070336w

    Article  CAS  PubMed  Google Scholar 

  24. O. A. Gerasko, E. A. Mainicheva, M. I. Naumova, M. Neumaier, M. M. Kappes, S. Lebedkin, D. Fenske, and V. P. Fedin. Inorg. Chem., 2008, 47, 8869. https://doi.org/10.1021/ic8008317

    Article  CAS  PubMed  Google Scholar 

Download references

Funding

The reported study was funded by RFBR and the Government of the Novosibirsk Region within scientific project No. 20-43-540006.

The XRD data were obtained with the XRD Facility of NIIC SB RAS.

The article is based on the materials of the 10th National Conference on Crystal Chemistry.

Author information

Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    E. A. Kovalenko, I. V. Andrienko, D. G. Samsonenko & V. P. Fedin

Authors
  1. E. A. Kovalenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. I. V. Andrienko
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. D. G. Samsonenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. V. P. Fedin
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to E. A. Kovalenko.

Ethics declarations

The authors declare that they have no conflict of interests.

Additional information

Russian Text © The Author(s), 2021, published in Zhurnal Strukturnoi Khimii, 2021, Vol. 62, No. 12, pp. 1935-1941.https://doi.org/10.26902/JSC_id83834

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Kovalenko, E.A., Andrienko, I.V., Samsonenko, D.G. et al. CRYSTAL STRUCTURE OF La(III), Pr(III), AND Eu(III) COMPLEXES WITH A MACROCYCLIC CAVITAND CUCURBIT[6]URIL. J Struct Chem 62, 1819–1825 (2021). https://doi.org/10.1134/S0022476621120015

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0022476621120015

Keywords

Search

Navigation