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A NOVEL MERCURY COORDINATION COMPOUND WITH YELLOW PHOTOLUMINESCENCE

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Abstract

The solvothermal reaction of 4,4′-bipyridine (Bipy) and mercury nitrate in a mixed acetonitrile/water solution leads to a novel mercury coordination compound with the in situ formation of cyanide ions Hg(Bipy)(CN)2 (1). Its structure is determined by single crystal X-ray diffraction (XRD), and further characterized by powder XRD, elemental analysis, and IR spectroscopy. Compound 1 exhibits a 1D zigzag [Hg(Bipy)(CN)2]n chain structure. The solid-state photoluminescent properties of 1 are also investigated.

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Authors and Affiliations

  1. Chongqing Key Laboratory of Green Synthesis and Applications, College of Chemistry, Chongqing Normal University, Chongqing, People’s Republic of China

    Y. -L. Tao, Z. Zhao, Q. -T. Zhu, O. Wang & X. Liu

  2. Luoyang Polytechnic, Luoyang, People’s Republic of China

    Z. -H. Zhu

Authors
  1. Y. -L. Tao
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  2. Z. -H. Zhu
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  3. Z. Zhao
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  4. Q. -T. Zhu
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  5. O. Wang
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  6. X. Liu
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Correspondence to X. Liu.

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Russian Text © The Author(s), 2021, published in Zhurnal Strukturnoi Khimii, 2021, Vol. 62, No. 11, pp. 1921-1928.https://doi.org/10.26902/JSC_id84218

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Tao, Y.L., Zhu, Z.H., Zhao, Z. et al. A NOVEL MERCURY COORDINATION COMPOUND WITH YELLOW PHOTOLUMINESCENCE. J Struct Chem 62, 1810–1817 (2021). https://doi.org/10.1134/S0022476621110184

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  • DOI: https://doi.org/10.1134/S0022476621110184

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