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CRYSTAL STRUCTURE OF THE NORFLUOROCURARINE QUATERNIZATION PRODUCTS

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Abstract

Methyl iodide, bromoethylene bromide monohydrate, and hydroxymethylene-, chloromethylene bromide hemihydrate are obtained as quaternary salts by quaternization of the indole alkaloid norfluorocurarine, and their crystal structures are investigated. In the studied quaternary salts, there is an intramolecular hydrogen bond of the N–H…O=C type. In an acidic medium, a salt of the norfluorocurarine quaternization product crystallizes as a cocrystal consisting of hydroxymethylene bromide and chloromethylene bromide.

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Authors and Affiliations

  1. Yunusov Institute of Chemistry of Plant Substances, Academy of Sciences of the Republic of Uzbekistan, Tashkent, Republic of Uzbekistan

    Sh. M. Adizov

  2. National University of Uzbekistan, Tashkent, Republic of Uzbekistan

    Sh. M. Adizov & B. Tashkhodzhaev

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  1. Sh. M. Adizov
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  2. B. Tashkhodzhaev
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Correspondence to Sh. M. Adizov.

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Russian Text © The Author(s), 2021, published in Zhurnal Strukturnoi Khimii, 2021, Vol. 62, No. 11, pp. 1878-1884.https://doi.org/10.26902/JSC_id83827

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Adizov, S.M., Tashkhodzhaev, B. CRYSTAL STRUCTURE OF THE NORFLUOROCURARINE QUATERNIZATION PRODUCTS. J Struct Chem 62, 1767–1773 (2021). https://doi.org/10.1134/S0022476621110135

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  • DOI: https://doi.org/10.1134/S0022476621110135

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