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SYNTHESIS AND CRYSTAL STRUCTURE OF PENTANUCLEAR HETEROMETALLIC Pd(II)–La(III) ACETATE COMPLEX

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Abstract

The structure of a novel pentanuclear heterometallic complex [Pd3La2(OOCMe)12(MeCOOH)4] with an unusual ratio of metals 3Pd:2La is studied by XRD. The complex is prepared by the reaction of palladium acetate [Pd3(OOCMe)6] with lanthanum acetate [La(OOCMe)3·1.5H2O]. The molecule of the complex contains two heterometallic binuclear fragments [PdLa(OOCMe)5(MeCOOH)2] connected to the structure-forming fragment [Pd(OOCMe)2] via bridging acetate groups and hydrogen bonds of coordinated acetic acid.

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia

    I. A. Yakushev, N. V. Cherkashina, N. S. Smirnova & M. N. Vargaftik

  2. Higher Chemical College of Russian Academy of Sciences, Mendeleev University of Chemical Technology of Russia, Moscow, Russia

    M. A. Dyuzheva

  3. Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Russia

    A. B. Kornev

Authors
  1. I. A. Yakushev
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  2. M. A. Dyuzheva
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  3. N. V. Cherkashina
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  4. A. B. Kornev
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  5. N. S. Smirnova
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  6. M. N. Vargaftik
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Correspondence to I. A. Yakushev.

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Russian Text © The Author(s), 2021, published in Zhurnal Strukturnoi Khimii, 2021, Vol. 62, No. 10, pp. 1616-1620.https://doi.org/10.26902/JSC_id80820

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Yakushev, I.A., Dyuzheva, M.A., Cherkashina, N.V. et al. SYNTHESIS AND CRYSTAL STRUCTURE OF PENTANUCLEAR HETEROMETALLIC Pd(II)–La(III) ACETATE COMPLEX. J Struct Chem 62, 1511–1515 (2021). https://doi.org/10.1134/S0022476621100048

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  • DOI: https://doi.org/10.1134/S0022476621100048

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