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SYNTHESIS AND CRYSTAL STRUCTURE OF [LRe(CO)3(O2CC3F7)]

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Abstract

This work reports the synthesis and structural characterization of two heteroleptic complexes based on a stable {Re(CO)3}+ group. At the first stage, complexes with diimine ligands [LRe(CO)3Br] (L = 2,2’-bipyridine, bpy; 1,10-phenanthroline, phen) are obtained from [Re(CO)5Br]. At the second stage, their treatment with silver perfluorobutyrate leads to the formation of [LRe(CO)3(O2CC3F7)]. Both complexes are structurally characterized, their IR and luminescence spectra are described.

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  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    P. A. Abramov

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Russian Text © The Author(s), 2021, published in Zhurnal Strukturnoi Khimii, 2021, Vol. 62, No. 9, pp. 1513-1521.https://doi.org/10.26902/JSC_id79933

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Abramov, P.A. SYNTHESIS AND CRYSTAL STRUCTURE OF [LRe(CO)3(O2CC3F7)]. J Struct Chem 62, 1416–1424 (2021). https://doi.org/10.1134/S0022476621090109

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