Skip to main content
SpringerLink
Log in

1H NMR STUDY OF MIXED-LIGAND LANTHANIDE COMPLEXES. STOICHIOMETRY AND TEMPERATURE SENSITIVITY OF PARAMAGNETIC CHEMICAL SHIFTS OF PRASEODYMIUM β-DIKETONATES AND THEIR COMPOUNDS WITH 18-CROWN-6

  • Published:
Journal of Structural Chemistry Aims and scope Submit manuscript

Abstract

Complexes [(Pr(DPM)3)2], [Pr(DPM)3(18-crown-6)], [(Pr(DPM)3)2(18-crown-6)], [Pr(DPM)(PTA)(18-crown-6)]+ and the temperature sensitivity of paramagnetic lanthanidine-induced shifts of these complexes in CDCl3 solution are characterized by 1H NMR. The NMR methods are used to estimate the possibility of forming inclusive complexes in CDCl3 solution upon the interaction of lanthanide tris-β-diketonates with 18-crown-6 in the case of a more branched ligand than PTA (e.g., DPM). Upon the interaction of [(Pr(DPM)3)2] and 18-crown-6, the [Pr(DPM)3(18-crown-6)] forms prevail in solution. The obtained results indicate that the studied coordination compounds can be considered as 1H NMR paramagnetic lanthanide probes for local temperature control in organic solutions using the analysis of paramagnetic lanthanidine-induced shifts.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4

Similar content being viewed by others

REFERENCES

  1. B. Bleaney. J. Magn. Reson., 1972, 8, 91-100, DOI: 10.1016/0022-2364(72)90027-3.

    Article  CAS  Google Scholar 

  2. J. Koehler and J. Meiler. Prog. Nucl. Magn. Reson. Spectrosc., 2011, 59, 360-389, DOI: 10.1016/j.pnmrs.2011.05.001.

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  3. D. K. Danovich, V. G. Zakzhevsy, and V. K. Voronov. J. Struct. Chem., 1986, 27(2), 320-321.

    Article  Google Scholar 

  4. C. Piguet and C. F. G. C. Geraldes. Paramagnetic NMR Lanthanide Induced Shifts for Extracting Solution Structures. In: Handbook on the Physics and Chemistry of Rare Earths, Vol. 33 / Eds. K. A. Gschneidner, J.-C. G. Bünzli,and V. K. Pecharsky. Elsevier Science: Amsterdam, Netherlands, 2003, 353-463.

  5. N. S. Poluektov, E. V. Malinka, S. B. Beltiukova, and V. N. Pastuschok. Dokl. Akad. Nauk Ukr. SSR, Ser. B: Geol., Khim. Biol. Nauki, 1984, 8, 51-54.

  6. A. V. Bogatsky, V. F. Zolin, L. G. Koreneva, L. G. Lukianenko, J. A. Popkov, and V. A. Scharkin. Russ. J. Coord. Chem., 1984, 10(8), 1048-1053.

  7. J. G. Bunsli, G. A. Leonard, and D. Planchered. Helv. Chim. Acta, 1986, 69, 288-297.

  8. Y. Gangdi and F. Yuguo. Chin. J. Appl. Chem, 1986, 3(1), 3-6.

  9. N. F. Krasnova, J. A. Simonov, B. K. Belsky, A. T. Fedorova, and V. V. Jakschin. Kristallografiya, 1986, 31(6), 1099-1104.

  10. J. G. Bunzli and D. Wessner. Coord. Chem. Rev., 1984, 60, 191-253.

    Article  Google Scholar 

  11. J. G. Bunzli and D. Wessner. Helv. Chim. Acta, 1981, 64(2), 582-598.

    Article  Google Scholar 

  12. J. G. Bunzli, B. Klein, G. Chapnis, and K. J. Schenk. Inorg. Chem., 1982, 21, 808-812.

  13. M. Khiraoka. Crown Compounds: Properties and Applications. Mir: Moscow, 1986.

  14. R. B. King and P. R. Heckley. J. Am. Chem. Soc., 1974, 96(10), 3118-3123.

    Article  CAS  Google Scholar 

  15. D. H. Metkalf, R. D. Chiradelli, and R. A. Palmer. Inorg. Chem., 1985, 4, 634.

  16. M. E. Harman, F. A. Hart, M. B. Hursthouse, and G. E. Hawkes. J. Chem. Soc., Chem. Commun., 1976, 11, 396-397.

    Article  Google Scholar 

  17. J. D. J. Barker-Dirks, J. E. Cooke, A. M. P. Galas, J. S. Ghotra, C. J. Gray, and F. A. Hart. J. Chem. Soc., Dalton Trans., 1980, 11, 2191-2193.

    Article  Google Scholar 

  18. J. F. Desreux and G. Duyckaerts. Inorg. Chim. Acta, 1979, 35(1), L313-L315.

    Article  CAS  Google Scholar 

  19. L. Lunde, V. V. Jastrebov, and I. A. Sulin-Berguchin. Russ. J. Gen. Chem., 1989, 59(8), 1848-1853.

  20. J. G. Gorbunova, A. G. Martynov, K. P. Birin, and A. J. Zivadse. Russ. J. Inorg. Chem., 2021, 66(2), 1-16.

    Article  CAS  Google Scholar 

  21. S. P. Babailov and J. G. Kriger. J. Struct. Chem., 1993, 33(3), 156-159.

  22. S. P. Babailov and D. A. Mainichev. J. Inclusion Phenom. Macrocyclic Chem., 2002, 43, 187-193.

    Article  CAS  Google Scholar 

  23. S. P. Babailov. Inorg. Chem., 2012, 51, 1427-1433, DOI: 10.1021/ic201662q.

    Article  CAS  PubMed  Google Scholar 

  24. G. A. Catton, M. E. Harman, F. A. Hart, G. E. Hawkes, and G. P. Moss. J. Chem. Soc., Dalton Trans., 1978, 181-184.

  25. S. P. Babailov and L. D. Nikulina. J. Inclusion Phenom. Macrocyclic Chem., 2005, 51(1), 103-109, DOI: 10.1007/s10847-004-4673-5.

    Article  CAS  Google Scholar 

  26. P. A. Stabnikov, I. V. Korolkov, N. V. Pervukhina, O. V. Antonova, P. E. Plyusnin, S. A. Prokhorova, and S. V. Larionov. Russ. J. Gen. Chem., 2015, 85(1), 144-153.

    Article  CAS  Google Scholar 

  27. P. A. Stabnikov, G. I. Zharkova, A. I. Smolentsev, N. V. Pervukhina, and V. V. Krisyuk. J. Struct. Chem., 2011, 52(3), 577-584.

    Article  CAS  Google Scholar 

  28. K. J. Eisentraut and R. E. Sievers. J. Am. Chem. Soc, 1965, 87, 5254-5256.

    Article  CAS  Google Scholar 

  29. Cambridge Structural Database System. Version 5.42, 2020 (updates Nov. 2020).

  30. P. A. Stabnikov, N. V. Pervukhina, N. V. Kuratieva, N. A. Kryuchkova, I. V. Korolkov, S. Urkasym kyzy, S. V. Sysoev, and S. P. Babailov. Polyhedron, 2021, 198, 115077, DOI: 10.1016/j.poly.2021.115077.

    Article  CAS  Google Scholar 

  31. S. P. Babailov. Progr. Nucl. Magn. Reson. Spectrosc., 2009, 54(3-4), 183-194.

    Article  CAS  Google Scholar 

  32. S. P. Babailov and A. V. Goryunova. J. Macroheterocycles, 2012, 5(2), 178-181, DOI: 10.6060/mhc2012.120469b.

    Article  CAS  Google Scholar 

  33. S. P. Babailov. J. Macroheterocycles, 2012, 5(3), 249-251.

    Article  CAS  Google Scholar 

  34. S. P. Babailov. J. Inclusion Phenom. Macrocyclic Chem., 2014, 80(3), 377-381, DOI: 10.1007/s10847-014-0423-5.

    Article  CAS  Google Scholar 

  35. S. P. Babailov. Prog. Nucl. Magn. Reson. Spectrosc., 2008, 52(1), 1-21, DOI: 10.1016/j.pnmrs.2007.04.002.

    Article  CAS  Google Scholar 

  36. S .P. Babailov, J. G. Kriger, T. N. Martynova, and L. D. Nikulina. J. Struct. Chem., 1990, 31(3), 44-47.

    Article  Google Scholar 

  37. S .P. Babailov. Sens. Actuators, B, Chem., 2017, 251, 108-111.

    Article  CAS  Google Scholar 

  38. S .P. Babailov, E. N. Zapolotsky, and E. S. Fomin. Polyhedron, 2013, 65, 332-336.

    Article  CAS  Google Scholar 

  39. S. P. Babailov and E. N. Zapolotsky. Polyhedron, 2020, 114908.

    Article  CAS  Google Scholar 

Download references

Funding

This work was funded by the Russian Science Foundation (project No. 20-63-46026).

Author information

Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    S. P. Babailov, P. A. Stabnikov & S. V. Tkachev

  2. Voevodsky Institute of Chemical Kinetics and Combustion, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    A. I. Kruppa

Authors
  1. S. P. Babailov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. P. A. Stabnikov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. S. V. Tkachev
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. A. I. Kruppa
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to S. P. Babailov.

Ethics declarations

The authors declare that they have no conflict of interests.

Additional information

Russian Text © The Author(s), 2021, published in Zhurnal Strukturnoi Khimii, 2021, Vol. 62, No. 8, pp. 1270-1276.https://doi.org/10.26902/JSC_id78484

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Babailov, S.P., Stabnikov, P.A., Tkachev, S.V. et al. 1H NMR STUDY OF MIXED-LIGAND LANTHANIDE COMPLEXES. STOICHIOMETRY AND TEMPERATURE SENSITIVITY OF PARAMAGNETIC CHEMICAL SHIFTS OF PRASEODYMIUM β-DIKETONATES AND THEIR COMPOUNDS WITH 18-CROWN-6. J Struct Chem 62, 1184–1190 (2021). https://doi.org/10.1134/S0022476621080035

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0022476621080035

Keywords

Search

Navigation