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SYNTHESIS AND STRUCTURE OF A RHENIUM TETRAHEDRAL CLUSTER COMPLEX WITH THE {Re4(PO)4}4+ CORE

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Abstract

By a high-temperature reaction of rhenium(III) iodide and red phosphorus with an excess of sodium cyanide followed by recrystallization from an aqueous solution a new tetrahedral [{Re4(PO)4}(CN)12]8– anionic cluster complex is obtained. It is isolated as a salt of the composition Na8[{Re4(PO)4}(CN)12] 18H2O·MeOH. The structure of the obtained compound is determined by X-ray crystallography. The compound crystallizes in the monoclinic crystal system, P21/n space group, unit cell parameters a = 26.826(3) Å, b = 11.4975(12) Å, c = 29.141(3) Å, β = 97.879(2)°, V = 8903.2(16) Å3, Z = 8.

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Funding

The work was supported by RFBR (project No. 19-53-12019) and the German Research Center (project No. ME914-31-1).

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    A. S. Pronin, K. A. Brylev & Yu. V. Mironov

  2. Institute of Inorganic Chemistry, University of Tübingen, Tübingen, Germany

    M. Ströbele & H. -J. Meyer

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  1. A. S. Pronin
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  2. K. A. Brylev
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  3. M. Ströbele
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  4. H. -J. Meyer
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  5. Yu. V. Mironov
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Correspondence to A. S. Pronin.

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Russian Text © The Author(s), 2021, published in Zhurnal Strukturnoi Khimii, 2021, Vol. 62, No. 7, pp. 1157-1163.https://doi.org/10.26902/JSC_id76140

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Pronin, A.S., Brylev, K.A., Ströbele, M. et al. SYNTHESIS AND STRUCTURE OF A RHENIUM TETRAHEDRAL CLUSTER COMPLEX WITH THE {Re4(PO)4}4+ CORE. J Struct Chem 62, 1079–1085 (2021). https://doi.org/10.1134/S002247662107012X

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  • DOI: https://doi.org/10.1134/S002247662107012X

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