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COMPLEX SALT [Pd(NH3)4][Pd(NH3)3NO2][RhOx3]·H2O AS A PROSPECTIVE PRECURSOR OF Pd–Rh NANOALLOYS. CRYSTAL STRUCTURE OF Na3[RhOx3]·4H2O

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Abstract

New complex salts [Pd(NH3)4][Pd(NH3)3NO2][RhOx3]·H2O and Na3[RhOx3]·4H2O are prepared. The crystal structures of obtained compounds are determined by XRD. Complex salt [Pd(NH3)4] [Pd(NH3)3NO2][RhOx3]·H2O is studied by powder XRD, IR spectroscopy, and elemental analysis. The state of rhodium(III) in oxalate solutions is studied by NMR. Thermal behavior of [Pd(NH3)4][Pd(NH3)3NO2] [RhOx3]·H2O in various gas atmospheres shows that final thermolysis products in reducing and inert atmospheres are solid solutions Pd1–xRhx.

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REFERENCES

  1. C. Te Hsieh, Y. F. Chen, and P. Y. Yu. Int. J. Hydrogen Energy, 2015, 40, 14857-14865, DOI: 10.1016/j.ijhydene.2015.09.035.

    Article  CAS  Google Scholar 

  2. F. Mauriello, H. Ariga-Miwa, E. Paone, R. Pietropaolo, S. Takakusagi, and K. Asakura. Catal. Today, 2019, 1-7, DOI: 10.1016/j.cattod.2019.06.071.

    Article  CAS  Google Scholar 

  3. P. A. J. Bagot, K. Kruska, D. Haley, X. Carrier, E. Marceau, M. P. Moody, and G. D. W. Smith. J. Phys. Chem., 2014, 118, 26130-26138, DOI: 10.1021/jp508144z.

    Article  CAS  Google Scholar 

  4. H. Fang, J. Yang, M. Wen, and Q. Wu. Adv. Mater., 2018, 30, 1-10, DOI: 10.1002/adma.201705698.

    Article  CAS  Google Scholar 

  5. S. Shan, J. Luo, L. Yang, and C. J. Zhong. Catal. Sci. Technol., 2014, 4, 3570-3588, DOI: 10.1039/c4cy00469h.

    Article  CAS  Google Scholar 

  6. W. Zhang, S. Shan, J. Luo, A. Fisher, J. F. Chen, C. J. Zhong, J. Zhu, and D. Cheng. J. Phys. Chem., 2017, 121, 11010-11020, DOI: 10.1021/acs.jpcc.6b10814.

    Article  CAS  Google Scholar 

  7. Z. Wang and X. Bai. J. Mol. Struct., 2020, 1219, 128538, DOI: 10.1016/j.molstruc.2020.128538.

    Article  CAS  Google Scholar 

  8. Z. Zhou, J. Ouyang, H. Yang, and A. Tang. Appl. Clay Sci., 2016, 121-122, 63-70, DOI: 10.1016/j.clay.2015.12.017.

    Article  CAS  Google Scholar 

  9. F. Le Normand, J. Barrault, R. Breault, L. Hilaire, and A. Kiennemann. J. Phys. Chem., 1991, 95, 257-269, DOI: 10.1021/j100154a050.

    Article  CAS  Google Scholar 

  10. A. A. Vedyagin, A. M. Volodin, V. O. Stoyanovskii, R. M. Kenzhin, E. M. Slavinskaya, I. V. Mishakov, P. E. Plyusnin, and Y. V. Shubin. Catal. Today, 2014, 238, 80-86, DOI: 10.1016/j.cattod.2014.02.056

    Article  CAS  Google Scholar 

  11. H. Wei, X. Wei, X. Yang, G. Yin, A. Wang, X. Liu, Y. Huang, and T. Zhang. Chin. J. Catal., 2015, 36, 160-167, DOI: 10.1016/S1872-2067(14)60254-0.

    Article  CAS  Google Scholar 

  12. P. E. Plyusnin, E. V. Makotchenko, Y. V. Shubin, I. A. Baidina, I. V. Korolkov, L. A. Sheludyakova, and S. V. Korenev. J. Mol. Struct., 2015, 1100, 174-179, DOI: 10.1016/j.molstruc.2015.07.023.

    Article  CAS  Google Scholar 

  13. I. A. Garkul, A. V. Zadesenets, I. V. Korolkov, I. A. Baidina, and S. V. Korenev. J. Struct. Chem., 2020, 61(5), 719-726, DOI: 10.1134/S0022476620050078.

    Article  CAS  Google Scholar 

  14. S. V. Korenev, A. B. Venediktov, Y. V. Shubin, S. A. Gromilov, and K. V. Yusenko. J. Struct. Chem., 2003, 44(1), 46-59, DOI: 10.1023/A:1024980930337.

    Article  CAS  Google Scholar 

  15. F. Khosravi and H. Mansouri-Torshizi. J. Biomol. Struct. Dyn., 2018, 36, 512-531, DOI: 10.1080/07391102.2017.1281171.

    Article  CAS  PubMed  Google Scholar 

  16. A. Zadesenets, E. Filatov, P. Plyusnin, I. Baidina, V. Dalezky, Y. Shubin, S. Korenev, and A. Bogomyakov. Polyhedron, 2011, 30, 1305-1312, DOI: 10.1016/j.poly.2011.02.012.

    Article  CAS  Google Scholar 

  17. A. N. Nana, D. Haynes, H. Vezin, C. Minaud, P. Shankhari, B. P. T. Fokwa, and J. Nenwa. J. Mol. Struct., 2020, 1220, 1-9, DOI: 10.1016/j.molstruc.2020.128642.

    Article  CAS  Google Scholar 

  18. A. V. Zadesenets, I. A. Garkul, E. Y. Filatov, P. E. Plyusnin, T. N. Filippov, T. I. Asanova, I. V. Korolkov, I. A. Baidina, I. P. Asanov, and S. V. Korenev. J. Therm. Anal. Calorim., 2019, 138, 111-121, DOI: 10.1007/s10973-019-08254-0.

    Article  CAS  Google Scholar 

  19. Sintez Kompleks. Soyed. Metal. Platin. gruppy: Spravochnik (Synth. Complex Compd. Platinum Group Met.: A Handbook) [in Russian] / Ed. I. I. Chernyaev. Nauka: Moscow, 1964.

  20. Powder Diffraction File, PDF-2/Release 2009. International Centre for Diffraction Date: USA, 2009.

  21. G. M. Sheldrick. SHELXTL-97, Progr. Refinement Cryst. Struct. Univ. of Göttingen: Göttingen, Germany, 1998.

  22. NETZSCH Proteus Thermal Analysis, v. 6.1.0. Selb/ NETZSCH-Gerätebau GmbH: Bayern, Germany, 2013.

  23. Bruker Apex3 software suite: Apex3, SADABS v. 2016/2, TWINABS and SAINT v. 2018.7-2. Bruker AXS: Madison, WI, 2017.

  24. G. M. Sheldrick. Acta Crystallogr., Sect. A, 2015, 71, 3-8.

    Article  Google Scholar 

  25. G. M. Sheldrick. Acta Crystallogr., Sect. C, 2015, 71, 3-8.

    Article  Google Scholar 

  26. O. V. Dolomanov, L. J. Bourhis, R. J. Gildea, J. A. K. Howard, and H. Puschmann. J. Appl. Crystallogr., 2009, 42, 339.

    Article  CAS  Google Scholar 

  27. A. B. Venediktov, A. A. Kazakova, M. A. Fedotov, and A. B. Belyaev. Koord. Khim. 1989, 15, 822-824.

  28. F. P. Boer, V. B. Carter. and J. W. Turley. Inorg. Chem., 1971, 10, 651-661.

    Article  CAS  Google Scholar 

  29. R. Kuroda. Inorg. Chem., 1991, 30, 4954-4959, DOI: 10.1021/ic00026a020.

    Article  CAS  Google Scholar 

  30. L. A. Kushch, L. S. Kurochkina, E. B. Yagubskii, G. V. Shilov, S. M. Aldoshin, V. A. Emelyanov, Y. N. Shvachko, V. S. Mironov, D. Schaniel, T. Woike, C. Carbonera, and C. Mathonière. Eur. J. Inorg. Chem., 2006, 4074-4085, DOI: 10.1002/ejic.20060027.

    Article  CAS  Google Scholar 

  31. R. Tian, Y. Yan, C. Zhang, L. Wang, and Q. Pan. Acta Crystallogr., Sect. E: Crystallogr. Commun., 2012, 68, m914-m915, DOI: 10.1107/S1600536812026414.

    Article  CAS  Google Scholar 

  32. K. Nakamoto. Infrared and Raman Spectra of Inorganic and Coordination Compounds. Wiley-Interscience: New York, 1986.

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Funding

The work was funded by the Russian Science Foundation (project No. 16-13-10192).

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    M. V. Gladysheva, P. E. Plyusnin, S. N. Vorobyeva, V. Yu. Komarov, S. V. Tkachev, Yu. V. Shubin & S. V. Korenev

  2. Novosibirsk State University, Novosibirsk, Russia

    M. V. Gladysheva

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  1. M. V. Gladysheva
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  2. P. E. Plyusnin
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  3. S. N. Vorobyeva
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  4. V. Yu. Komarov
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  5. S. V. Tkachev
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  6. Yu. V. Shubin
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Correspondence to P. E. Plyusnin.

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Russian Text © The Author(s), 2021, published in Zhurnal Strukturnoi Khimii, 2021, Vol. 62, No. 5, pp. 839-851.https://doi.org/10.26902/JSC_id72911

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Gladysheva, M.V., Plyusnin, P.E., Vorobyeva, S.N. et al. COMPLEX SALT [Pd(NH3)4][Pd(NH3)3NO2][RhOx3]·H2O AS A PROSPECTIVE PRECURSOR OF Pd–Rh NANOALLOYS. CRYSTAL STRUCTURE OF Na3[RhOx3]·4H2O. J Struct Chem 62, 782–793 (2021). https://doi.org/10.1134/S0022476621050140

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