Skip to main content
SpringerLink
Log in

THE FIRST EXAMPLE OF A DYSPROSIUM–ZIRCONIUM CHALCOGENIDE COMPLEX

  • Published:
Journal of Structural Chemistry Aims and scope Submit manuscript

Abstract

The synthesis approach based on the acid-base interaction is used to synthesize 4f/4d heterometallic chalcogenide compounds. By the interaction of the acidic hydrosulfide complex of zirconium \([\text{Cp}'_2\text{Zr}{{(\text{SH})}_{\text{2}}}]\) (Cp′ = η5-t-BuC5H4) with basic \([\text{Cp}_{2}^{\mathbf{*}}\text{Dy}(\text{allyl})]\) a heterometallic \({{[\text{Cp}'_2\text{Zr}(\mu \text{-S})({{\mu }_{3}}\text{-S})\text{DyCp}_{2}^{\mathbf{*}}]}_{2}}\) complex is obtained, which is the first example of dysprosium–zirconium chalcogenide coordination clusters (1). The structure of the complex is determined by single crystal Xray diffraction. New crystalline modifications of the known sulfide complex of zirconium \({{[\text{Cp}'_2\text{Zr}(\mu \text{-S})]}_{2}}\), being the decomposition product of \([\text{Cp}'_2\text{Zr}{{(\text{SH})}_{\text{2}}}]\) in solution, are also structurally characterized.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Scheme 1

Similar content being viewed by others

REFERENCES

  1. K. Liu, W. Shi, and P. Cheng. Coord. Chem. Rev., 2015, 289-290, 74-122.

    Article  CAS  Google Scholar 

  2. A. Chakraborty, J. Goura, P. Kalita, A. Swain, G. Rajaraman, and. Chandrasekhar. Dalton Trans., 2018, 47, 8841-8864.

    Article  CAS  PubMed  Google Scholar 

  3. S. Tanase and J. Reedijk. Coord. Chem. Rev., 2006, 250, 2501-2510.

    Article  CAS  Google Scholar 

  4. M. Andruh, J.-P. Costes, C. Diaz, and S. Gao. Inorg. Chem., 2009, 48, 3342-3359.

    Article  CAS  PubMed  Google Scholar 

  5. B. Monteiro, J. T. Coutinho, and L. C. J. Pereira. In: Lanthanide-Based Multifunctional Materials. Elsevier, 2018, 233-261.

  6. A. Kornienko, S. Banerjee, G. A. Kumar, R. E. Riman, T. J. Emge, and J. G. Brennan. J. Am. Chem. Soc., 2005, 127, 14008-14014.

    Article  CAS  PubMed  Google Scholar 

  7. M. Brewer, J. Lee, and J. G. Brennan. Inorg. Chem., 1995, 34, 5919-5924.

    Article  CAS  Google Scholar 

  8. M. Berardini, T. Emge, and J. G. Breenan. J. Am. Chem. Soc., 1994, 116, 6941-6942.

    Article  CAS  Google Scholar 

  9. S. Banerjee, J. Sheckelton, T. J. Emge, and J. G. Brennan. Inorg. Chem., 2010, 49, 1728-1732.

    Article  CAS  PubMed  Google Scholar 

  10. S. N. Konchenko, T. Sanden, N. A. Pushkarevsky, R. Köppe, and P. W. Roesky. Chem. - Eur. J., 2010, 16, 14278-14280.

    Article  CAS  PubMed  Google Scholar 

  11. M. Y. Afonin, T. S. Sukhikh, A. Y. Konokhova, and S. N. Konchenko. Russ. J. Coord. Chem., 2018, 44, 147-154.

    Article  CAS  Google Scholar 

  12. M. Y. Afonin, T. S. Sukhikh, A. Y. Konokhova. and S. N. Konchenko. J. Struct. Chem., 2020, 61(9), 1312.

  13. H.-X. Li, Y.-J. Zhu, M.-L. Cheng, and Z.-G. Ren. Coord. Chem. Rev., 2006, 250, 2059-2092.

    Article  CAS  Google Scholar 

  14. A. Kumar, R. E. Riman, and J. G. Brennan. Coord. Chem. Rev., 2014, 273-274, 111-124.

    Article  CAS  Google Scholar 

  15. M. V. Butovskii and R. Kempe. New J. Chem., 2015, 39, 7544-7558

    Article  CAS  Google Scholar 

  16. G. Tainturier, M. Fahim, and B. Gautheron. J. Organomet. Chem., 1989, 373, 193-202.

    Article  CAS  Google Scholar 

  17. S. Demir, J. M. Zadrozny, M. Nippe, and J. R. Long. J. Am. Chem. Soc., 2012, 134, 18546-18549.

    Article  CAS  PubMed  Google Scholar 

  18. Apex3 software suite: Apex3, SADABS-2016/2 and SAINT, version 2018.7-2. Bruker AXS Inc.: Madison, WI, 2017.

  19. G. M. Sheldrick. Acta Crystallogr., Sect. A: Found. Adv., 2015, 71, 3-8.

    Article  Google Scholar 

  20. G. M. Sheldrick. Acta Crystallogr., Sect. C: Struct. Chem., 2015, 71, 3-8.

    Article  Google Scholar 

  21. O. V. Dolomanov, L. J. Bourhis, R. J. Gildea, J. A. K. Howard, and H. Puschmann. J. Appl. Crystallogr., 2009, 42, 339-341.

    Article  CAS  Google Scholar 

  22. M. D. Pluth and Z. J. Tonzetich. Chem. Soc. Rev., 2020, 49, 4070-4134.

    Article  CAS  PubMed  Google Scholar 

  23. M. Fahim and G. Tainturier. J. Organomet. Chem., 1986, 301, C45-C48.

    Article  CAS  Google Scholar 

  24. Y. Rong and G. Parkin. Aust. J. Chem., 2013, 66, 1306.

    Article  CAS  Google Scholar 

  25. R. Gyepes, I. Císařová, J. Pinkas, J. Kubišta, M. Horáček, and K. Mach. Eur. J. Inorg. Chem., 2013, 3316-3322.

    Article  CAS  Google Scholar 

  26. G. Tainturier, B. Gautheron, and M. Fahim. J. Organomet. Chem., 1985, 290, C4-C6.

    Article  CAS  Google Scholar 

  27. F. Bottomley, D. F. Drummond, G. O. Egharevba, and P. S. White. Organometallics, 1986, 5, 1620-1625.

    Article  CAS  Google Scholar 

  28. B. Li, J. Li, H. W. Roesky, and H. Zhu. J. Am. Chem. Soc., 2015, 137, 162-164.

    Article  CAS  PubMed  Google Scholar 

  29. M. A. Casado, M. A. Ciriano, F. J. Lahoz, L. A. Oro, and J. J. Pérez-Torrente. J. Organomet. Chem., 2016, 812, 123-134.

    Article  CAS  Google Scholar 

  30. M. A. F. Hernandez-Gruel, J. J. Pérez-Torrente, M. A. Ciriano, A. B. Rivas, F. J. Lahoz, I. T. Dobrinovitch, and L. A. Oro. Organometallics, 2003, 22, 1237-1249.

    Article  CAS  Google Scholar 

Download references

Funding

The work was supported by the Russian Science Foundation (grant No. 16-13-10294).

Author information

Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    A. Yu. Konokhova, M. Yu. Afonin, T. S. Sukhikh & S. N. Konchenko

  2. Novosibirsk State University, Novosibirsk, Russia

    A. Yu. Konokhova & S. N. Konchenko

Authors
  1. A. Yu. Konokhova
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. M. Yu. Afonin
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. T. S. Sukhikh
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. S. N. Konchenko
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to S. N. Konchenko.

Ethics declarations

The authors declare that they have no conflict of interests.

Additional information

Russian Text © The Author(s), 2021, published in Zhurnal Strukturnoi Khimii, 2021, Vol. 62, No. 5, pp. 758-764.https://doi.org/10.26902/JSC_id72873

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Konokhova, A.Y., Afonin, M.Y., Sukhikh, T.S. et al. THE FIRST EXAMPLE OF A DYSPROSIUM–ZIRCONIUM CHALCOGENIDE COMPLEX. J Struct Chem 62, 704–710 (2021). https://doi.org/10.1134/S0022476621050061

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0022476621050061

Keywords

Search

Navigation