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SYNTHESIS AND THERMAL PROPERTIES OF DOUBLE COMPLEX SALT: CHLOROPENTAAMMINECHROMIUM(III) BIS(OXALATO)PALLADATE

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Abstract

Double complex salt [Cr(NH3)5Cl][Pd(C2O4)2] is synthesized for the first time. From the powder X-ray diffraction data it is found that the structure of the compound is triclinic with unit cell parameters: a = 3.225(3) Å, b = 10.290(6) Å, c = 11.390(6) Å, α = 116.5(2)°, β = 97.9(2)°, γ = 91.2(5)°, V = 334.5 Å3 (room temperature). The thermal properties are studied in detail in different gaseous atmospheres using powder X-ray diffraction, IR and Raman spectroscopy to identify intermediate and final thermolysis products. The sequence of stages of the thermal destruction of the double complex salt in inert and reducing atmospheres and the formation of the final thermolysis product (a double-phase mixture of palladium and chromium(III) oxide) are established.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    V. I. Lagunova, E. Yu. Filatov, P. E. Plyusnin, V. Yu. Komarov, S. A. Martynova & S. V. Korenev

  2. Novosibirsk State University, Novosibirsk, Russia

    V. I. Lagunova

Authors
  1. V. I. Lagunova
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  2. E. Yu. Filatov
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  3. P. E. Plyusnin
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  4. V. Yu. Komarov
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  5. S. A. Martynova
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  6. S. V. Korenev
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Correspondence to V. I. Lagunova.

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Russian Text © The Author(s), 2021, published in Zhurnal Strukturnoi Khimii, 2021, Vol. 62, No. 4, pp. 594-601.https://doi.org/10.26902/JSC_id71134

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Lagunova, V.I., Filatov, E.Y., Plyusnin, P.E. et al. SYNTHESIS AND THERMAL PROPERTIES OF DOUBLE COMPLEX SALT: CHLOROPENTAAMMINECHROMIUM(III) BIS(OXALATO)PALLADATE. J Struct Chem 62, 555–562 (2021). https://doi.org/10.1134/S0022476621040065

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