Skip to main content
SpringerLink
Log in

SESQUITERPENE LACTONES OF THE EUDESMAN TYPE FROM ARTEMISIA SEMIARIDA: ISOLATION AND SPATIAL STRUCTURE

  • Published:
Journal of Structural Chemistry Aims and scope Submit manuscript

Abstract

As a result of studying the chemical composition of the Kazakh endemic Artemisia semiarida ((Krasch. Et Lavr.) Filat.), sesquiterpene γ-lactones of the eudesman type are isolated for the first time: taurine, 8α-acetoxytaurine, and 8α-hydroxytaurine. Their spatial structures are determined by Xray diffraction (XRD). New eudesmanolide named 8α-acetoxy-2-en-taurine is also isolated. Based on the single crystal XRD data, its structure is 1-keto-8α-acetoxy-7α,6,11β(H)-eudesm-2,4-diene-6,12-olide.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4

Similar content being viewed by others

REFERENCES

  1. K. S.Rybalko. Natural Sesquiterpene Lactones [in Russian]. Meditsina: Moscow, 1978.

  2. M. D. Mashkovskii. Medicinal Resources [in Russian]. Novaya volna: Moscow, 2019.

  3. Flora of Kazakhstan [in Russian] / Eds N. V. Pavlov. Vol. 9. Nauka: Alma-Ata, 1966.

  4. Bruker. APEX2. Software Suite for Crystallographic Programs. Bruker AXS: Madison, WI, USA, 2009.

  5. G. M. Sheldrick. Acta Crystallogr., Sect. A, 2008, 64, 112–122.

  6. G. M. Sheldrick. Acta Crystallogr., Sect. C, 2015, 71, 3–8.

  7. Z. Caliskan, N. Goren, and W. H. Watson. J. Chem. Crystallogr., 2004, 34(5), 307–310.

  8. M. Calleri, G. Chiari, and D. Viterbo. Acta Crystallogr., Sect. C, 1983, 39(8), 1115–1117.

  9. N. F. Kochetova, K. S. Rybalko, V. I. Sheichenko, and L. P. Tolstykh. Khim. Prir. Soedin., 1968, 4, 205–207.

  10. A. H. Mericli, J. Jakupovic, F. Bohlmann, B. Damadyan, N. Ozhatay, and B. Cubukcu. Planta Med., 1988, 54(5), 447–449.

  11. A. B. Trendafilova, M. N. Todorova, and C. V. Gussev. Phytochemistry, 1996, 42(2), 469–471.

  12. F. H. Allen, O. Kennard, D. G. Watson, L. Brammer, A. G. Orpen, and R. Taylor. J. Chem. Soc. Perkin Trans. 2, 1987, S1–S19.

  13. Atlas of Steroid Structure / Eds. W. L. Duax and D. A. Norton. Vol. 1. IFI/PLENUM: New-York, 1975.

  14. M. Nogradi. Stereochemistry. Basic Concepts and Applications. Akademia Kiado: Budapest, 1981.

Download references

Author information

Authors and Affiliations

  1. Buketov Karaganda State University, Karaganda, Republic of Kazakhstan

    K. M. Turdybekov

  2. Karaganda State Medical University, Karaganda, Republic of Kazakhstan

    B. B. Rakhimova

  3. Karaganda State Technical University, Karaganda, Republic of Kazakhstan

    D. M. Turdybekov

  4. International Research and Production Holding “PhytoChemistry”, Karaganda, Republic of Kazakhstan

    S. M. Adekenov

Authors
  1. K. M. Turdybekov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. B. B. Rakhimova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. D. M. Turdybekov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. S. M. Adekenov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to K. M. Turdybekov.

Ethics declarations

The authors declare that they have no conflict of interests.

Additional information

Translated from Zhurnal Strukturnoi Khimii, 2021, Vol. 62, No. 2, pp. 301-307 https://doi.org/10.26902/JSC_id68358 .

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Turdybekov, K.M., Rakhimova, B.B., Turdybekov, D.M. et al. SESQUITERPENE LACTONES OF THE EUDESMAN TYPE FROM ARTEMISIA SEMIARIDA: ISOLATION AND SPATIAL STRUCTURE. J Struct Chem 62, 285–291 (2021). https://doi.org/10.1134/S002247662102013X

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S002247662102013X

Keywords

Search

Navigation