Skip to main content
SpringerLink
Log in

Eu(III) AND Tb(III) COMPLEXES BASED ON DIPHENYL(PYRIMIDIN-2-YL)PHOSPHINE OXIDE: SYNTHESIS, STRUCTURE, AND PHOTOLUMINESCENT PROPERTIES

  • Published:
Journal of Structural Chemistry Aims and scope Submit manuscript

Abstract

Coordination compounds [Eu{Ph2P(O)Pym}2(NO3)3] (1) and [Tb{Ph2P(O)Pym}2(MeOH)(NO3)3] (2) are synthesized by the interaction of Eu(III) and Tb(III) nitrates with diphenyl(pyrimidin-2-yl)phosphine oxide (Ph2P(O)Pym). According to single crystal XRD data, the crystal structures of 1 and 2 consist of molecules of mononuclear complexes. The Ph2P(O)Pym ligand is bidentate chelating and monodentate in complexes 1 and 2 respectively; coordination polyhedra of the Ln atom are N2O8 in 1 and O9 in 2. The presence of C–H⋯O hydrogen bonds between the neighboring molecules of the complexes leads to the formation of dimeric ensembles organized in chains (in 1) and layers (in 2) by weaker hydrogen bonds. The complexes exhibit metal-centered photoluminescence in the solid state at 300 K with long lifetimes of excited states (τ > 1 ms) and luminescence quantum yields φ = 28% and 14% for complexes 1 and 2 respectively.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6

Similar content being viewed by others

REFERENCES

  1. A. W. G. Platt. Coord. Chem. Rev., 2017, 340, 62.

  2. Y. Hirai, T. Nakanishi, and Y. Hasegawa. J. Lumin., 2016, 170, 801.

  3. J. C. G. Bünzli. Coord. Chem. Rev., 2015, 293–294, 19.

  4. T. Harada, Y. Hasegawa, Y. Nakano, M. Fujiki, M. Naito, T. Wada, Y. Inoue, and T. Kawai. J. Alloys Compd., 2009, 488, 599.

  5. M. Congiu, M. Alamiry, O. Moudam, S. Ciorba, P. R. Richardson, L. Maron, A. C. Jones, B. S. Richards, and N. Robertson. Dalton Trans., 2013, 42, 13537.

  6. H. Xu, L.-H. Wang, X.-H. Zhu, K. Yin, G.-Yu Zong, X.-Y. Hou, and W. Huang. J. Phys. Chem. B, 2006, 110, 3023.

  7. H. Xu, K. Yin, and W. Huang. Chem. Eur. J., 2007, 13, 10281.

  8. Md. A. Subhan, Y. Hasegawa, T. Suzuki, S. Kaizaki. and Y. Shozo. Inorg. Chim. Acta, 2009, 362, 136.

  9. V. Divya, R. O. Freire, and M. L. P. Reddy. Dalton Trans., 2011, 40, 3257.

  10. D. B. A. Raj, B. Francis, M. L. P. Reddy, R. R. Butorac, V. M. Lynch, and A. H. Cowley. Inorg. Chem., 2010, 49, 9055.

  11. N. E. Borisova, A. V. Kharcheva, S. V. Patsaeva, L. A. Korotkov, S. Bakaev, M. D. Reshetova, K. A. Lyssenko, E. V. Belova, and B. F. Myasoedov. Dalton Trans., 2017, 46, 2238.

  12. S. Mal, M. Pietraszkiewicz, and O. Pietraszkiewicz. J. Coord. Chem., 2015, 68, 367.

  13. S. Biju, N. Gopakumar, J.-C. G. Bünzli, R. Scopelliti, H. K. Kim, M. L. P. Reddy. Inorg. Chem., 2013, 52, 8750.

  14. Y. Hasegawa, R. Hieda, K. Miyata, T. Nakagawa, and T. Kawai. Eur. J. Inorg. Chem., 2011, 32, 4978.

  15. Y. Hirai, T. Nakanishi, K. Miyata, K. Fushimi, and Y. Hasegawa. Mater. Lett., 2014, 130, 91.

  16. K. Miyata, Y. Konno, T. Nakanishi, A. Kobayashi, M. Kato, K. Fushimi, and Y. Hasegawa. Angew. Chem., Int. Ed., 2013, 52, 6413.

  17. K. Miyata, T. Nakanishi, K. Fushimi, and Y. Hasegawa. J. Photochem. Photobiol., A, 2012, 235, 35.

  18. L. J. Charbonniere, R. Ziessel, M. Montalti, L. Prodi, N. Zaccheroni, C. Boehme, and G. Wipff. J. Am. Chem. Soc., 2002, 124, 7779.

  19. S. Xu, M. Liu, H.-L. Han, Z.-F. Li, Q.-H. Jin, W. Su, Y.-Y. Chen, and J.-Y. Yao. Polyhedron, 2015, 85, 69.

  20. T. Harada, Y. Nakano, M. Fujiki, M. Naito, T. Kawai, and Y. Hasegawa. Inorg. Chem., 2009, 48, 11242.

  21. L. R. Melby, N. J. Rose, E. Abranmson, and J. C. Caris. J. Am.Chem. Soc., 1964, 86, 5117.

  22. F. H. Barnes, A. W. Kelly, H. Melzer, H. H. Patterson, and R. D. Pike. Z. Anorg. Allg. Chem., 2018, 644, 525.

  23. Y. Ma, S. Xu, X. Wang, M. Liu, Y.-X. Li, X.-L. Xin, and Q.-H. Jin. Z. Anorg. Allg. Chem., 2017, 643, 780.

  24. D. R. Cousins and F. A. Hart. J. Inorg. Nucl. Chem., 1967, 29, 1745.

  25. R. P. Feazell, J. B. Gary, K. K. Klausmeyer, J. A. Kautz, and C. W. Wong. J. Chem. Crystallogr., 2004, 34, 507.

  26. Y. P. Mascarenhas, R. H. de Almeida Santos, G. R. Leite, and O. A. Serra. J. Inorg. Nucl. Chem., 1973, 35, 2595.

  27. G. Valle, G. Casotto, P. L. Zanonato, and B. Zarli. Polyhedron, 1986, 5, 2093.

  28. W. Levason, E. H. Newman, and M. Webster. Polyhedron, 2000, 19, 2697.

  29. B. G. Vats, S. Kannan, M. Kumar, and M. G. B. Drew. ChemistrySelect, 2017, 2, 3683.

  30. M. T. Reetz, R. Demuth, and R. Goddard. Tetrahedron Lett., 1998, 39, 7089.

  31. CrysAlisPro 1.171.39.46. Rigaku Oxford Diffraction, 2018.

  32. G. M. Sheldrick. Acta Crystallogr., 2015, A71, 3.

  33. G. M. Sheldrick. Acta Crystallogr., 2015, C71, 3.

  34. V. Tsaryuk, V. Zolin, L. Puntus, V. Savchenko, J. Legendziewicz, J. Sokolnicki, and R. Szostak. J. Alloys Compd., 2000, 300–301, 184.

  35. I. R. Ferraro. J. Mol. Spectrosc., 1960, 4, 99.

  36. G. B. Deacon and J. H. S. Green. Spectrochim. Acta, Part A, 1968, 24, 845.

  37. W. T. Carnall and H. Crosswhite. Energy Levels Structure and Transition Probabilities of the Trivalent Lanthanides in LaF3, Argonne. National Laboratory Report. USA, 1977.

  38. Yu. A. Bryleva, L. A. Glinskaya, A. M. Agafontsev, M. I. Rakhmanova, A. S. Bogomyakov, T. S. Sukhikh, E. A. Gorbunova, A. V. Tkachev, and S. V. Larionov. J. Struct. Chem., 2019, 60(8), 1314.

Download references

Funding

The work was supported by RFBR within scientific project No. 19-73-00158.

Author information

Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    Yu. A. Bryleva, A. V. Artem’ev, L. A. Glinskaya, D. G. Samsonenko, M. I. Rakhmanova & M. P. Davydova

  2. Novosibirsk State University, Novosibirsk, Russia

    K. M. Yzhikova

Authors
  1. Yu. A. Bryleva
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. V. Artem’ev
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. L. A. Glinskaya
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. D. G. Samsonenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. M. I. Rakhmanova
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. M. P. Davydova
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. K. M. Yzhikova
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Yu. A. Bryleva.

Ethics declarations

The authors declare that they have no conflict of interests.

Additional information

Translated from Zhurnal Strukturnoi Khimii, 2021, Vol. 62, No. 2, pp. 280-291 https://doi.org/10.26902/JSC_id68351 .

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Bryleva, Y.A., Artem’ev, A.V., Glinskaya, L.A. et al. Eu(III) AND Tb(III) COMPLEXES BASED ON DIPHENYL(PYRIMIDIN-2-YL)PHOSPHINE OXIDE: SYNTHESIS, STRUCTURE, AND PHOTOLUMINESCENT PROPERTIES. J Struct Chem 62, 265–276 (2021). https://doi.org/10.1134/S0022476621020116

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0022476621020116

Keywords

Search

Navigation