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SYNTHESIS AND STRUCTURE OF A NEW NEODYMIUM COMPLEX WITH AN UNUSUAL TYPE OF COORDINATION OF THE BENZYL LIGAND

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Abstract

A reaction of \([{\text{Cp}'''}_{\text{2}}\,\text{NdI}]\) (1) (Cp′′′ = 1,3,4-tris(tert-butyl)cyclopentadienide) with BzK (Bz = C6H5CH2) in toluene is studied. The result of this reaction was expected to be Bz–substitution for I–, however, it is found that the main reaction product is a new binuclear neodymium complex [(Cp′′′BzNd)2O] (2), containing a bridging oxygen atom. Structures of (1) and (2) are determined by single crystal X-ray diffraction analysis.

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Funding

The work was supported by the Russian Science Foundation (grant No. 16-13-10294).

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    A. G. Demkin, B. Yu. Savkov, T. S. Sukhikh & S. N. Konchenko

  2. Novosibirsk State University, Novosibirsk, Russia

    A. G. Demkin & S. N. Konchenko

Authors
  1. A. G. Demkin
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  2. B. Yu. Savkov
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  3. T. S. Sukhikh
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  4. S. N. Konchenko
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Correspondence to S. N. Konchenko.

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Demkin, A.G., Savkov, B.Y., Sukhikh, T.S. et al. SYNTHESIS AND STRUCTURE OF A NEW NEODYMIUM COMPLEX WITH AN UNUSUAL TYPE OF COORDINATION OF THE BENZYL LIGAND. J Struct Chem 62, 116–122 (2021). https://doi.org/10.1134/S0022476621010145

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